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(a)
Interpretation: The synthesis of given compound from aniline as starting material is to be devised.
Concept introduction: The formation of diazonium salt from
(b)
Interpretation: The synthesis of given compound from aniline as starting material is to be devised.
Concept introduction: The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using cuprous halides or aryl cyanides using cuprous cyanides.
Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
(c)
Interpretation: The synthesis of given compound from aniline as starting material is to be devised.
Concept introduction: The formation of diazonium salt from aromatic amines takes place using sodium nitrite and hydrochloric acid at low temperatures. This process is known as diazotization. The diazonium salts can be converted to aryl halides using cuprous halides or aryl cyanides using cuprous cyanides.
Diazonium salts form azo compounds with aromatic phenols or aromatic amines.
Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride (Lewis acid). This alkylation reaction comes under the category of electrophilic aromatic substitution.
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Chapter 25 Solutions
ORGANIC CHEMISTRY
- What is the major organic product obtained from the following reaction? A. B. CI لله مللی حمله C. D. فيarrow_forwardidentify the reagents needed to come up with the compounds given. a. b. c. d. e. f. g. h. i.arrow_forwardDevise a synthesis of each compound from phenol (C6H5OH) and any other organic or inorganic reagents.arrow_forward
- Devise a synthesis of each compound from cyclohexene as the startingmaterial. More than one step is needed.arrow_forward16.69 Use the reactions in this chapter along with those learned in Chapters 11 and 12 to synthesize each compaund. You may use benzene, acetylene (HC=CH), ethanol, ethylene oxide, and any inorganic reagents. a. b. CI он C ON d. NO2arrow_forwardDevise a synthesis of each compound from benzene. но OH CH3 а. b. с. d.arrow_forward
- Devise a synthesis of each compound from cyclohexene as the starting material. More than one step is needed.arrow_forwardDevise a synthesis of compound A from the given starting materials. You may use any other inorganic reagents or organic alcohols. A was used to prepare aliskiren, a drug used to treat hypertension (see also Problem 5.7). CH,0 NH2 OH но. CHO Br CH,0. H2N. CH;0 CH30 A CH,0 Br Br aliskirenarrow_forwardDevise a synthesis of each compound from the given starting material(s). Albuterol is a bronchodilator and proparacaine is a local anesthetic.arrow_forward
- Devise a synthesis of each biologically active compound from benzenearrow_forward16.43 Draw the products of each reaction. a. b. d. HO C. H Lore L sob Br₂ FeBr3 e. NO₂ Br HNO3 H₂SO4 CI AICI 3 Cl₂ FeCl3 SO3 H₂SO4arrow_forwardDevise a synthesis of muscalure, the sex pheromone of the common housey, from acetylene and any other required reagents.arrow_forward
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