ORGANIC CHEMISTRY-PACKAGE
8th Edition
ISBN: 9780134647586
Author: Bruice
Publisher: PEARSON
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Textbook Question
Chapter 25.3, Problem 3P
Draw the structure of an optically inactive fat that, when hydrolyzed under acidic conditions, gives glycerol, one equivalent of lauric acid, and two equivalents of stearic acid.
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Draw the structure of an optically inactive fat that, when hydrolyzed under acidic conditions, gives glycerol, one equivalent of lauric acid, and two equivalents of stearic acid.
Draw the structure of an optically active fat that, when hydrolyzed under acidic conditions.
What is the structure of an optically inactive triacylglycerol that yields two moles of oleic acid and one mole of palmitic acid when hydrolyzed in aqueous acid?
Chapter 25 Solutions
ORGANIC CHEMISTRY-PACKAGE
Ch. 25.1 - Prob. 1PCh. 25.3 - Which has a higher melting point, glyceryl...Ch. 25.3 - Draw the structure of an optically inactive fat...Ch. 25.3 - Draw the structure of an optically active fat...Ch. 25.5 - Do the identities of R1 and R2 in phosphatidic...Ch. 25.5 - Membranes contain proteins, Integral membrane...Ch. 25.5 - Prob. 8PCh. 25.5 - The membrane phospholipids in deer have a higher...Ch. 25.6 - Treating PGC2 with a strong base such as sodium...Ch. 25.7 - Mark off the isoprene units in menthol, -selinene,...
Ch. 25.7 - Prob. 13PCh. 25.7 - Prob. 14PCh. 25.8 - Propose mechanisms for the Claisen condensation...Ch. 25.8 - Prob. 16PCh. 25.8 - Propose a mechanism for the conversion of...Ch. 25.8 - Propose a mechanism for the biosynthesis of...Ch. 25.8 - Propose a mechanism for the conversion of the E...Ch. 25.8 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.8 - Prob. 22PCh. 25.8 - Prob. 23PCh. 25.9 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25.10 - Prob. 26PCh. 25.10 - Prob. 27PCh. 25.10 - The acid component of a cholesterol ester is a...Ch. 25.10 - Prob. 29PCh. 25.10 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - An optically active fat, when completely...Ch. 25 - Prob. 33PCh. 25 - a. How many different triacylglycerols are there...Ch. 25 - Cardiolipins are found in heart muscles. Draw the...Ch. 25 - Nutmeg contains a simple, fully saturated...Ch. 25 - Draw the product that is obtained from the...Ch. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - 5-Androstene-3.17-dione is isomerized to...Ch. 25 - Prob. 44PCh. 25 - Eudesmol is a sesquiterpene found in eucalyptus....Ch. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Diethylstilbestrol (DES) was given to pregnant...
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- Identify the following fatty acid, and tell whether it is more likely to be found in peanut oil or in red meat:arrow_forwardA triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acidarrow_forwardA triglyceride can be optically active if it contains two or more different fatty acids.(a) Draw the structure of an optically active triglyceride containing one equivalent of myristic acid and two equivalentsof oleic acid.(b) Draw the structure of an optically inactive triglyceride with the same fatty acid composition.arrow_forward
- 1. Some marine plankton contain triacylglycerols formed from the polyunsaturated fatty acid (PUFA) such as: CH3CH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2CH=CHCH2COOH a) Draw the skeletal structure of the given PUFA showing the preffered stereogenic arrangement for a naturally-occuring lipid at each double bond. b) Write the systematic name of the fatty acid. c) What type of omega-n acid is this fatty acid? d) Would you expect this fatty acid to be a soild or liquid at room temperature?arrow_forwardA simple triacylglycerol is one that: a) Upon hydrolysis produces glycerol and three different fatty acids. b) Upon hydrolysis produces glycerol and at least two different fatty acids. c) Upon saponification gives glycerol and three fatty acid salts. d) Upon saponification gives three esters. e) Upon hydrolysis produces glycerol and three mol of a fatty acid.arrow_forwardare the fatty acid propyl esters (biodiesel) formed in acid-catalysed esterification of octanoic acid with 1-propanol more or less polar than glycerol?arrow_forward
- Can different fatty acids form esters on the same glycerol molecule? Is it possible for a trans-fatty acid to be synthesized from a cis-fatty acid? if so how? How many hydroxyl groups does the Sphingomyelin backbone contain?arrow_forwardWaste cooking oil contains free fatty acids as well as triacylglycerols. Draw the chemical equation (with molecular structures) for the acid-catalysed esterification of octanoic acid with 1-propanol (Fischer esterification). Show the product(s).arrow_forwardDraw the structure of a phosphoacylglycerol that contains glycerol, oleic acid and serine.arrow_forward
- Draw a triacylglycerol made from glycerol, myristic acid, palmitic acid, and oleic acid. Place palmitic acid at the middle position.arrow_forwardDraw a phosphoglyceride formed by the reaction of glycerol, 1 molecule of myristic acid, 1 molecule of linoleic acid, 1 phosphate and 1 molecule of ethanolamine. The drawing should be in the form found at physiological pH. Use a line drawing for the fatty acids. Becarful with the geometry of the unsaturated fatty acid. Make sure you attach the ethanolamine via the correct atom.arrow_forwardThe following triacylglycerol is composed of glycerol and A) two myristic acids and oleic acid B) two stearic acids and oleic acid C) two lauric acids and oleic acid D) myristic acid and two oleic acids E) myristic acid, lauric and oleic acidarrow_forward
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