ORGANIC CHEMISTRY-PACKAGE
8th Edition
ISBN: 9780134647586
Author: Bruice
Publisher: PEARSON
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Chapter 25.3, Problem 4P
Draw the structure of an optically active fat that, when hydrolyzed under acidic conditions, gives the same products as the fat in problem 3.
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Chapter 25 Solutions
ORGANIC CHEMISTRY-PACKAGE
Ch. 25.1 - Prob. 1PCh. 25.3 - Which has a higher melting point, glyceryl...Ch. 25.3 - Draw the structure of an optically inactive fat...Ch. 25.3 - Draw the structure of an optically active fat...Ch. 25.5 - Do the identities of R1 and R2 in phosphatidic...Ch. 25.5 - Membranes contain proteins, Integral membrane...Ch. 25.5 - Prob. 8PCh. 25.5 - The membrane phospholipids in deer have a higher...Ch. 25.6 - Treating PGC2 with a strong base such as sodium...Ch. 25.7 - Mark off the isoprene units in menthol, -selinene,...
Ch. 25.7 - Prob. 13PCh. 25.7 - Prob. 14PCh. 25.8 - Propose mechanisms for the Claisen condensation...Ch. 25.8 - Prob. 16PCh. 25.8 - Propose a mechanism for the conversion of...Ch. 25.8 - Propose a mechanism for the biosynthesis of...Ch. 25.8 - Propose a mechanism for the conversion of the E...Ch. 25.8 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.8 - Prob. 22PCh. 25.8 - Prob. 23PCh. 25.9 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25.10 - Prob. 26PCh. 25.10 - Prob. 27PCh. 25.10 - The acid component of a cholesterol ester is a...Ch. 25.10 - Prob. 29PCh. 25.10 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - An optically active fat, when completely...Ch. 25 - Prob. 33PCh. 25 - a. How many different triacylglycerols are there...Ch. 25 - Cardiolipins are found in heart muscles. Draw the...Ch. 25 - Nutmeg contains a simple, fully saturated...Ch. 25 - Draw the product that is obtained from the...Ch. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - 5-Androstene-3.17-dione is isomerized to...Ch. 25 - Prob. 44PCh. 25 - Eudesmol is a sesquiterpene found in eucalyptus....Ch. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Diethylstilbestrol (DES) was given to pregnant...
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- Draw a D-glucose structure and identify the pyran ring. Also, draw a D-fructose and identify the furan ring in the structure.arrow_forwardConsider the tetrasaccharide stachyose drawn below. Stachyose is found in white jasmine, soybeans, and lentils. Because humans cannot digest it, its consumption causes flatulence.a. Label all glycoside bonds.b. Classify each glycosidic linkage as α or β and use numbers to designate its location between two rings (e.g., 1→4-β).c. What products are formed when stachyose is hydrolyzed with H3O+?d. Is stachyose a reducing sugar?e. What product is formed when stachyose is treated with excess CH3I, Ag2O?f. What products are formed when the product in (e) is treated with H3O+?arrow_forwardBoth triglycerides shown below contained fatty acids that are 16 carbon long. However, one is classified as a fat, and the other is regarded as the oil. (A) How does one distinguish fat from oils? (B) Which triglyceride is the fat? Which one is oil?arrow_forward
- show the glycosidic linkage of b-D-galactose and b-D-galactose (show drawing)arrow_forwardPart 1 Show the complete steps and products of the Haworth Projection structure of the following saccharides. The males have to answer the structure of D-fructose and the females are the structure of D-galactose. Expanded structure of the given molecule Fischer Projection Haworth's structure [show the complete steps] Step 1 Step 2 Step 3 Part 2 Show the synthesis of disaccharide lactose. Give the expanded structure of the reactants. Give the expanded structure of the products. Part 3. Show the chemical reaction of D-ribose. Name the chemical reaction. Show here the chemical equation and name the products. Use the expanded structure. 1. 2. 3.arrow_forwardWhy are all of the elements in group 18 relatively unreactive, whereasthose in group 17 are very reactive?arrow_forward
- Given solution: 5%lactose, 5% glucose, 5% maltose, 5% fructose, 5% galactose, 5% arabinose, 5% sucrose, 5% starch, and water: Which of the sugar solutions gave a negative/positive test with Benedict’s reagent? Why? What is the purpose of this test? How are the carbohydrates differentiated by this test? What is the reaction involved in this test?arrow_forwardConsider the tetrasaccharide stachyose drawn below. Stachyose is found in white jasmine, soybeans, and lentils. Because humans cannot digest it, its consumption causes flatulence.a. Label all glycoside bonds.b. Classify each glycosidic linkage as αα or ββ and use numbers to designate its location between two rings (e.g., 1→→4-ββ)-c. What products are formed when stachyose is hydrolyzed with H33O++?d. Is stachyose a reducing sugar?e. What product is formed when stachyose is treated with excess CH33I, Ag22O?f. What products are formed when the product in (e) is treated with H33O++?arrow_forwardFrom Figure 18.7, arrange the following substances in order of increasing percentage of unsaturated fatty acids: chicken fat, beef fat, corn oil, butter, and sunflower oil.arrow_forward
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