ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
9th Edition
ISBN: 9780137249442
Author: Wade
Publisher: INTER PEAR
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Chapter 26, Problem 26.35SP
The polyester named Lactomer® is an alternating
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Poly(lactic acid) (PLA) has received much recent attention because the lactic acid monomer [CH3CH(OH)COOH] from which it is made can be obtained from carbohydrates rather than petroleum. This makes PLA a more “environmentally friendly” polyester. Draw the structure of PLA
A particularly strong and rigid polyester used for electronic parts is marketed under the trade name Glyptal. It is a polymer of terephthalic acid and glycerol. Draw a segment of the polymer and explain why it is so strong.
The polyester named Lactomer® is an alternating copolymer of lactic acid and glycolic acid. Lactomer is used for absorbable suture material because stitches of Lactomer hydrolyze slowly over a two-week period and do not have to be removed. The hydrolysis products, lactic acid and glycolic acid, are normal metabolites and do not provoke an inflammatory response. Draw the structure of the Lactomer polymer.
Chapter 26 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
Ch. 26.2A - Show the intermediate that would result if the...Ch. 26.2A - Prob. 26.2PCh. 26.2A - Prob. 26.3PCh. 26.2B - Prob. 26.4PCh. 26.2B - Prob. 26.5PCh. 26.2B - Chain branching occurs in cationic polymerization...Ch. 26.2C - Prob. 26.7PCh. 26.2C - Prob. 26.8PCh. 26.2C - Chain branching is not as common with anionic...Ch. 26.3 - Prob. 26.10P
Ch. 26.5 - Prob. 26.11PCh. 26.6 - Prob. 26.12PCh. 26.7A - Prob. 26.13PCh. 26.7B - Prob. 26.14PCh. 26.7B - Prob. 26.15PCh. 26.7C - a. Propose a mechanism for the reaction of...Ch. 26.7C - Prob. 26.17PCh. 26.7D - Prob. 26.18PCh. 26.7D - Prob. 26.19PCh. 26.7D - Prob. 26.20PCh. 26 - Prob. 26.21SPCh. 26 - Prob. 26.22SPCh. 26 - Poly(trimethylene carbamate) is used in...Ch. 26 - Prob. 26.24SPCh. 26 - Urylon fibers are used in premium fishing nets...Ch. 26 - Prob. 26.26SPCh. 26 - Prob. 26.27SPCh. 26 - Polyoxymethylene (polyformaldehyde) is the tough,...Ch. 26 - Prob. 26.29SPCh. 26 - Prob. 26.30SPCh. 26 - Prob. 26.31SPCh. 26 - Prob. 26.32SPCh. 26 - Prob. 26.33SPCh. 26 - Prob. 26.34SPCh. 26 - The polyester named Lactomer is an alternating...Ch. 26 - Prob. 26.36SP
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- In addition to glycolic and lactic acids (Section 30.6B), dissolving sutures can also be prepared from each of the following lactone monomers. Draw the structure of the polymer formed from each monomer.arrow_forwardPoly(vinyl alcohol), a hydrophilic polymer used in aqueous adhesives, is made by polymerizing vinyl acetate and then hydrolyzing the ester linkages. We have seen that basic hydrolysis destroys the Dacron polymer. Poly(vinyl acetate) is converted to poly(vinyl alcohol) by a basic hydrolysis of the ester groups. Why doesn’t the hydrolysis destroy the poly(vinyl alcohol)polymer?arrow_forwardDraw the structure of the polymer formed by chain-growthpolymerization of each monomerarrow_forward
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