Connect Online Access 1-Semester for Organic Chemistry

6th Edition

ISBN: 9781260475609

Author: SMITH, Janice

Publisher: Mcgraw-hill Higher Education (us)

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Concept explainers

Carbohydrates

Carbohydrates are the organic compounds that are obtained in foods and living matters in the shape of sugars, cellulose, and starch. The general formula of carbohydrates is Cn(H2O)2. The ratio of H and O present in carbohydrates is identical to water.

Starch

Starch is a polysaccharide carbohydrate that belongs to the category of polysaccharide carbohydrates.

Mutarotation

The rotation of a particular structure of the chiral compound because of the epimerization is called mutarotation. It is the repercussion of the ring chain tautomerism. In terms of glucose, this can be defined as the modification in the equilibrium of th…

L Sugar

A chemical compound that is represented with a molecular formula C6H12O6 is called L-(-) sugar. At the carbon’s 5th position, the hydroxyl group is placed to the compound’s left and therefore the sugar is represented as L(-)-sugar. It is capable of rotat…

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 26.9, Problem 21P

Interpretation Introduction

(a)

Interpretation: The given compound is to be classified as reducing or nonreducing sugar.

Concept introduction: A carbohydrate that contains hemiacetal is classified as reducing sugar whereas a carbohydrate which contains acetal is classified as nonreducing sugar. The reducing sugars are in equilibrium with an acyclic aldehyde.

Interpretation Introduction

(b)

Interpretation: The given compound is to be classified as reducing or nonreducing sugar.

Concept introduction: A carbohydrate that contains hemiacetal is classified as reducing sugar whereas a carbohydrate which contains acetal is classified as nonreducing sugar. The reducing sugars are in equilibrium with an acyclic aldehyde.

Interpretation Introduction

(c)

Interpretation: The given compound is to be classified as reducing or nonreducing sugar.

Concept introduction: A carbohydrate that contains hemiacetal is classified as reducing sugar whereas a carbohydrate which contains acetal is classified as nonreducing sugar. The reducing sugars are in equilibrium with an acyclic aldehyde.

Expert Solution & Answer

Chapter 26 Solutions

Connect Online Access 1-Semester for Organic Chemistry

Ch. 26.2 - Prob. 1P Ch. 26.2 - Prob. 2P Ch. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5P Ch. 26.2 - Prob. 6P Ch. 26.3 - Prob. 7P Ch. 26.3 - Prob. 8P Ch. 26.4 - Prob. 9P Ch. 26.4 - Prob. 10P

Ch. 26.6 - Prob. 11P Ch. 26.6 - Prob. 12P Ch. 26.6 - Prob. 13P Ch. 26.6 - Prob. 14P Ch. 26.6 - Prob. 15P Ch. 26.7 - Prob. 16P Ch. 26.7 - Draw a stepwise mechanism for the following...Ch. 26.7 - Prob. 18P Ch. 26.8 - Prob. 19P Ch. 26.9 - Prob. 20P Ch. 26.9 - Prob. 21P Ch. 26.9 - Draw the products formed when D-arabinose is...Ch. 26.9 - Prob. 23P Ch. 26.10 - Prob. 24P Ch. 26.10 - Prob. 25P Ch. 26.10 - Prob. 26P Ch. 26.10 - Prob. 27P Ch. 26.11 - Prob. 28P Ch. 26.11 - Prob. 29P Ch. 26.12 - Prob. 30P Ch. 26.12 - Prob. 31P Ch. 26.13 - Prob. 32P Ch. 26.13 - Prob. 33P Ch. 26.13 - Problem-28.35 Draw the structures of the...Ch. 26.13 - Prob. 35P Ch. 26 - 28.37 Convert each ball-and-stick model to a...Ch. 26 - Prob. 37P Ch. 26 - Prob. 38P Ch. 26 - 28.40 Convert each compound to a Fischer...Ch. 26 - Prob. 40P Ch. 26 - Prob. 41P Ch. 26 - 28.43 Draw a Haworth projection for each compound...Ch. 26 - Prob. 43P Ch. 26 - 28.45 Draw both pyranose anomers of each...Ch. 26 - Prob. 45P Ch. 26 - 28.50 Draw the products formed when D-altrose is...Ch. 26 - 28.58 Draw a stepwise mechanism for the following...Ch. 26 - Prob. 62P Ch. 26 - Prob. 63P Ch. 26 - Prob. 64P Ch. 26 - Prob. 65P Ch. 26 - Prob. 66P Ch. 26 - Prob. 67P Ch. 26 - Prob. 68P Ch. 26 - Prob. 69P Ch. 26 - Prob. 70P

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