ORGANIC CHEMISTRY (LOOSELEAF)
ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Chapter 28.5, Problem 13P
Interpretation Introduction

Interpretation: A mechanism that accounts for the formation of A and B is to be drawn.

Concept introduction: The radical polymerization of alkenes often utilizes a RO· radical as initiator. This initiator is obtained by the homolysis cleavage of weak peroxy bond (OO) in ROOR.

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Consider the following nucleophilc substitution. LOCH3 Br OCH3 в A a. Identify the reaction conditions A and specify the reaction mechanism for the nucleophilic substitution. Explain your choice. b. Explain why the transformation does not give rise to significant elimination. c. Which product(s) B is formed in the reaction? Please specify the stereochemistry clearly with reference to the reaction mechanism.
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