Identify each functional group located in the following rings. Which structure
represents a lactone-a cyclic ester- and which represents a lactam-a cyclic amide?
a. b. c. d.
(a)
Interpretation: The functional group present in the given ring and the structure that represent a lactone and a lactam is to be stated.
Concept introduction: The table representing the general formula of different functional groups according to IUPAC convention is given below.
General formula | Functional group | Functional group name |
Alcohol | ||
Aldehyde | ||
Ketone | ||
Amine | ||
Ether | ||
Ester |
Answer to Problem 3.33P
The functional group present in the given ring is amine. The given structure neither represents a lactone nor a lactam.
Explanation of Solution
The given structure is,
Figure 1
The given structure contains amine as a functional group. In the given structure, nitrogen is bonded to three carbon atoms. Therefore, the given ring is a tertiary amine.
Lactone is a cyclic ester, whereas lactam is a cyclic amide. Thus, the given structure neither represents a lactone nor a lactam.
The functional group present in the given ring is amine. The given structure neither represents a lactone nor a lactam.
(b)
Interpretation: The functional group present in the given ring and the structure that represent a lactone-cyclic ester and a lactam-a cyclic amide is to be stated.
Concept introduction: The table representing the general formula of different functional groups according to IUPAC convention is given below.
General formula | Functional group | Functional group name |
Alcohol | ||
Aldehyde | ||
Ketone | ||
Amine | ||
Ether | ||
Ester |
Answer to Problem 3.33P
The functional group present in the given ring is ether. The given structure neither represents a lactone nor a lactam.
Explanation of Solution
The given structure is,
Figure 2
The given structure contains ether as a functional group. The given functional group is in cyclic form. Therefore, the given structure is cyclic ether. Lactone is a cyclic ester, whereas lactam is a cyclic amide. Thus, the given structure neither represents a lactone nor a lactam.
The functional group present in the given ring is ether. The given structure neither represents a lactone nor a lactam.
(c)
Interpretation: The functional group present in the given ring and the structure that represent a lactone-cyclic ester and a lactam-a cyclic amide is to be stated.
Concept introduction: The table representing the general formula of different functional groups according to IUPAC convention is given below.
General formula | Functional group | Functional group name |
Alcohol | ||
Aldehyde | ||
Ketone | ||
Amine | ||
Ether | ||
Ester |
Answer to Problem 3.33P
The functional group present in the given ring is ester. The given structure represents a lactone-cyclic ester.
Explanation of Solution
The given structure is,
Figure 3
In the given structure, the functional group present is ester. The given functional group is in cyclic form. Therefore, the given structure represents a lactone-cyclic ester.
The functional group present in the given ring is ester. The given structure represents a lactone-cyclic ester.
(d)
Interpretation: The functional group present in the given ring and the structure that represent a lactone-cyclic ester and a lactam-a cyclic amide is to be stated.
Concept introduction: The table representing the general formula of different functional groups according to IUPAC convention is given below.
General formula | Functional group | Functional group name |
Alcohol | ||
Aldehyde | ||
Ketone | ||
Amine | ||
Ether | ||
Ester |
Answer to Problem 3.33P
The functional group present in the given ring is amide. The given structure represents a lactam-a cyclic amide.
Explanation of Solution
The given structure is,
Figure 4
In the given structure, the functional group present is amide. The given functional group is in cyclic form. Therefore, the given structure represents a lactam-a cyclic amide.
The functional group present in the given ring is amide. The given structure represents a lactam-a cyclic amide.
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Chapter 3 Solutions
ORGANIC CHEMISTRY LSLF W/CONNECT >BI<
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