Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 3, Problem 3B.5E
Interpretation Introduction

Interpretation:

The entropy change of 1kg aluminum on cooling and also the energy removed as heat on cooling have to be calculated.

Concept Information:

Change in entropy on heating at constant volume: the change in entropy when the temperature is changed from Ti to Tf. The greater the heat capacity of substance, the change in entropy increases by increasing temperature. A high heat capacity implies that a lot of heat is required to produce a given change in temperature must be more powerful than for when the heat capacity is low, and the entropy increase is correspondingly high.

ΔS=Cln(TfTi)

Where,

C is the heat capacity of a substance,

Tf is the final temperature of the system,

Ti is the initial temperature of the system.

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