General Chemistry: Principles and Modern Applications - With Solutions Manual and Modified MasteringChemistry Code
11th Edition
ISBN: 9780134641003
Author: Petrucci
Publisher: PEARSON
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Chapter 3, Problem 63E
Write a formula for (a) the chloride of titanium having Tiin the
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Consider Palmitic acid C16H32O2, a common fatty acid used in the manufacture of soap. A solution of palmitic acid is prepared by mixing 112 g palmitic acid with 725 mL of benzene C6H6. The density of the resulting solution is 0.902 g/mL.
Palmitic acid (molar mass = 256 g/mol and density = 0.852 g/mL); Benzene (molar mass = 78 g/mol and density = 0.879 g/mL)
A. What is the %m/m of the solution?
B. What is the molarity of the solution?
C. What is the mole fraction of the solvent?
Cocaine (C17H21O4N) is a natural substance found in the leaves of the coca plant, which has been used for centuries as a local anesthetic and stimulant. Illegal cocaine arrives in the USA either as a pure compound or as the hydrochloride salt (C17H21O4NHCl). At 25oC, the salt is very soluble in water (2.50 kg/L), but pure cocaine is much less so (1.70 g/L).
What is the maximum amount of salt (in gram) that can dissolve in 50.0 mL of water? [1 mark.]
When a 25 mL aqueous solution that contains 62.50 g of the salt is treated with NaOH, the salt is converted to pure cocaine. How much water (in liters) is needed additionally to dissolve the formed pure cocaine? Round your final answer off to two decimal points.
C17H21O4NHCl(aq) + NaOH(aq) → C17H21O4N(aq) + H2O(l) + NaCl(aq)
What is the mass of fish, in kilograms, that one would have to consume to obtain a fatal dose of mercury, if the fish contains 30 parts per million of mercury by weight? (Assume that all the mercury from the fish ends up asmercury(II) chloride in the body and that a fatal dose is 0.20 g of HgCl2.) How many pounds of fish is this?
Chapter 3 Solutions
General Chemistry: Principles and Modern Applications - With Solutions Manual and Modified MasteringChemistry Code
Ch. 3 - Refer to the color scheme given Figure 3-3, and...Ch. 3 - Give the molecular formulas for the molecules...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Give the structure formulas of the molecules shown...Ch. 3 - Calculate the total number of (a) atoms one...Ch. 3 - Determine the mass, in grams, of a. 7.34molNO2 b....Ch. 3 - The amino acid methionine, which is essential in...Ch. 3 - Determine the number of moles of Br2 in a sample...Ch. 3 - Without doing detailed calculations, explain which...Ch. 3 - Without doing detailed calculations, determine...
Ch. 3 - Determine the number of moles of a. N2O4 in a 115...Ch. 3 - Determine the mass, in grams, of a. 2.10102 molS2...Ch. 3 - The content of is 15.5g/100 mLblood. The molar...Ch. 3 - In white phosphorus, P atoms are joined into P,...Ch. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - For the mineral torbernite, Cu( UO2)2( PO4)2,8H2O...Ch. 3 - For the compound Ge[S( CH 2 )4CH2]4 determine a....Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Determine the mass percent O in the mineral...Ch. 3 - Determine the mass percent H in the hydrocarbon...Ch. 3 - Prob. 22ECh. 3 - Determine the mass percent of each of the elements...Ch. 3 - Prob. 24ECh. 3 - Determine the percent, by mass,of the indicated...Ch. 3 - All of the following minerals are semiprecious or...Ch. 3 - Without doing calculations, arrange the following...Ch. 3 - Prob. 28ECh. 3 - Two oxides of sulfur have nearly identical...Ch. 3 - An oxide of chromium used in chrome plating has a...Ch. 3 - Diethylene glycol, used to de-ice aircraft, is a...Ch. 3 - Prob. 32ECh. 3 - Determine the empirical formula of (a) the...Ch. 3 - Prob. 34ECh. 3 - A compound of carbon and hydrogen consists of...Ch. 3 - Selenium, an element used in the manufacture of...Ch. 3 - Indigo, the dye for blue jeans, has a percent...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - The element X forms the compound XOCI2 containing...Ch. 3 - Prob. 41ECh. 3 - Two compounds of CI and X are found to have...Ch. 3 - A 0.1888 g sample of a hydrocarbon produces 0.6260...Ch. 3 - Para-cresol (p-cresol) is used as a disinfectant...Ch. 3 - Dimethylhydrazine is a carbon-hydrogen-nitrogen...Ch. 3 - Prob. 46ECh. 3 - Without doing detailed calculations, explain which...Ch. 3 - Prob. 48ECh. 3 - A 1.562 g sample of the alcohol CH2CHOHCH2CH2 is...Ch. 3 - Prob. 50ECh. 3 - Indicate the oxidation state of the underlined...Ch. 3 - Indicate the oxidation state of S in (a) SO42 (b)...Ch. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Hydrogen and oxygen usually have oxidation states...Ch. 3 - Prob. 57ECh. 3 - Name these compounds: (a)Ba(...Ch. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - Prob. 61ECh. 3 - Prob. 62ECh. 3 - Write a formula for (a) the chloride of titanium...Ch. 3 - Write formula for (a) an oxide of nitrogen with N...Ch. 3 - Prob. 65ECh. 3 - Supply the formula for the acids: (a) hydrofluoric...Ch. 3 - Name the following compounds and specify which...Ch. 3 - Prob. 68ECh. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - Anhydrous CuSO4 can be used to dry liquids in...Ch. 3 - Anhydrous sodium sulfate, Na2SO4 absorbs water...Ch. 3 - A certain hydrate is found to have the composition...Ch. 3 - An 8.129 g sample of MgSO4H2O is heated until all...Ch. 3 - Prob. 75ECh. 3 - Prob. 76ECh. 3 - Prob. 77ECh. 3 - Prob. 78ECh. 3 - Prob. 79ECh. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - The mineral spodumene has the empirical formula...Ch. 3 - Prob. 84IAECh. 3 - Prob. 85IAECh. 3 - The important natural sources of boron compounds...Ch. 3 - Prob. 87IAECh. 3 - By analysis, a compound was found to contain 26.58...Ch. 3 - Prob. 89IAECh. 3 - What is the molecular formula of a hydrocarbon...Ch. 3 - A hydrocarbon mixture consists of 601% by mass of...Ch. 3 - A 0.732 g mature of methane, CH4 and ethane, C2H5...Ch. 3 - The density of a mixture of H2SO4 and water is...Ch. 3 - Prob. 94IAECh. 3 - Prob. 95IAECh. 3 - Prob. 96IAECh. 3 - Prob. 97IAECh. 3 - Prob. 98IAECh. 3 - The metal M forms the sulfate M2( SO4)2. A 0.738 g...Ch. 3 - Prob. 100IAECh. 3 - Prob. 101IAECh. 3 - Prob. 102IAECh. 3 - A 1.013 g sample of ZnSO4H2O is dissolved in water...Ch. 3 - The iodide ion in a 1.552 g sample of the compound...Ch. 3 - Prob. 105IAECh. 3 - The insecticide dieldrin contains carbon, oxygen,...Ch. 3 - Prob. 107IAECh. 3 - The atomic mass of Bi is to be determined by...Ch. 3 - A piece of gold (Au) foil measuring 0.25mm15mm is...Ch. 3 - Prob. 110IAECh. 3 - Prob. 111IAECh. 3 - All-purpose fertilizers contain the essential...Ch. 3 - A hydrate of copper(II) sulfate, when heated, goes...Ch. 3 - Prob. 114FPCh. 3 - Prob. 115SAECh. 3 - Prob. 116SAECh. 3 - Prob. 117SAECh. 3 - Prob. 118SAECh. 3 - Prob. 119SAECh. 3 - Three of the following formulas might be ether an...Ch. 3 - Prob. 121SAECh. 3 - Prob. 122SAECh. 3 - Iron is present red blood and acts to carry oxygen...Ch. 3 - Prob. 124SAECh. 3 - Prob. 125SAECh. 3 - Prob. 126SAECh. 3 - Prob. 127SAECh. 3 - Prob. 128SAECh. 3 - Prob. 129SAECh. 3 - Which compound has a molar mass of...Ch. 3 - Prob. 131SAECh. 3 - Prob. 132SAECh. 3 - A hydrate of Na2SO2 contains almost exactly 50%...Ch. 3 - Malachite is a common copper-containing mineral...Ch. 3 - Prob. 135SAECh. 3 - Ibuprofen is a compound used in painkiller. When a...Ch. 3 - Prob. 137SAE
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- Cocaine (C₁₇H₂₁O₄N) is a natural substance found in cocaleaves, which have been used for centuries as a local anestheticand stimulant. Illegal cocaine arrives in the United States eitheras the pure compound or as the hydrochloride salt(C₁₇H₂₁O₄NHCl). At 25C, the salt is very soluble in water(2.50 kg/L), but cocaine is much less so (1.70 g/L). (a) Whatis the maximum amount (in g) of the salt that can dissolve in50.0 mL of water? (b) If the solution in part (a) is treated withNaOH, the salt is converted to cocaine. How much additionalwater (in L) is needed to dissolve it?arrow_forwardConsider Palmitic acid C16H32O2, a common fatty acid used in the manufacture of soap. A solution of palmitic acid is prepared by mixing 112 g palmitic acid with 725 mL of benzene C6H6. The density of the resulting solution is 0.902 g/mL. Palmitic acid (molar mass = 256 g/mol and density = 0.852 g/mL); Benzene (molar mass = 78 g/mol and density = 0.879 g/mL) 1. What is the % m/m of the solution? 2. What is the mole fraction of the solvent? 3. What is the molarity of the solution? Based from the calculated molarity of the solution in #3, you are to prepare 250 mL of the said molar concentration. If you have an available 2M stock solution of Palmitic acid, How many mL of the 2M palmitic acid stock solution will you need? and; 4. How many mL of solvent do you need to add to the amount gotten from the 2M Palmitic acid stock solution in order to prepare 250 mL total volume of your desired solution?arrow_forwardJoseph Priestly prepared oxygen in 1774 by heating red mercury(II) oxide with sunlight focused through a lens. How much heat is required to decompose exactly 1 mole of red HgO(s) to Hg(l) and O2(g) under standard conditions?arrow_forward
- One of the sources of iron is magnetite, Fe3O4 (FeO and Fe2O3 mixed), which reacts with coke (carbon) to produce iron in the liquid state and carbon monoxide. If we assume that coke is pure carbon, how much is supplied to produce 10,000 metric tons of iron?arrow_forwardA sampe compound of xenon and fluroine conatains moleucles of a single type; XeFn, where n is a whoel number. If 9.03 x1020 of these XeFn ole cules have a mass of 0.311g, hwat is the value of n?arrow_forwardA 1.00 g sample of a magnesium-aluminum alloy yields 0.107 g H2 when treated with an excess of HCl(aq). What is the percentage by mass of Al in the alloy? [Hint: This is the inverse of Example 4-16. To solve this problem, let m and 1.00 - m be the masses of Al and Mg, respectively, and then use these masses in the setup above to develop an equation that relates m to the total mass of H2 obtained. Then solve for m.]arrow_forward
- A well is punched into a slab of gelatin and a solution ofequimolar amounts of NaCl and KCl is placed in it. After anhour the concentration of Na+ and K+ present in the well ismeasured. Which ion, Na+ or K+, would be present ingreater abundance in the well? Explain your answer.arrow_forwardConsider Palmitic acid C16H32O2, a common fatty acid used in the manufacture of soap. A solution of palmitic acid is prepared by mixing 112 g palmitic acid with 725 mL of benzene C6H6. The density of the resulting solution is 0.902 g/mL. Palmitic acid (molar mass = 256 g/mol and density = 0.852 g/mL); Benzene (molar mass = 78 g/mol and density = 0.879 g/mL) A. What is the molarity of the solution? B. How many mL of the 2M palmitic acid stock solution will you need? Final answer must be rounded off to 2 decimal places, and shall NOT have any units.arrow_forwardWhat are the names of the fundamental laws which explain the properties of massand define one of them.arrow_forward
- a student carries out this chemical reaction in a beaker Zn+CuCl2 -> Cu+ZnCl2 after the reaction has come to completion, what should the student expect to find in the beaker ?arrow_forwardThe present average concentration (mass percent) of magnesium ions in seawater is 0.13%. A chemistry textbook estimates that if 1.00 × 108 tons Mg were taken out of the sea each year, it would take one million years for the Mg concentration to drop to 0.12%. Do sufficient calculations to either verify or refute this statement. Assume that Earth is a sphere with a diameter of 8000 mi, 67% of which is covered by oceans to a depth of 1 mi, and that no Mg is washed back into the oceans at any time.arrow_forwardWhat is the mass of fish, in kilograms, that one would have to consume to obtain a fatal dose of mercury, if the fish contains 30 parts per million of mercury by weight? (Assume that all the mercury from the fish ends up as mercury (II) chloride in the body and that a fatal dose is 0.20 g of HgCl2.) How many pounds of fish is this?arrow_forward
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