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ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Question
Chapter 30, Problem 30.42P
Interpretation Introduction
Interpretation: A stepwise mechanism for the anionic
Concept introduction: An
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Students have asked these similar questions
Draw the structure of the polymer that results from anionic polymerization of p-trichloromethylstyrene (CCl,CgH,CH=CH2) using
ethylene oxide as the electrophile to terminate the chain.
Draw a stepwise mechanism for the anionic polymerization of styrene (CH2=CHPh) to form polystyrene – [CH2CHPh]n – using BuLi as the initiator. Use CO2 as the electrophile that terminates the chain mechanism.
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(8-10
C
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CH₂
어
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• You do not have to consider stereochemistry.
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• Do not include lone pairs in your answer. They will not be considered in the grading.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
• Separate structures with + signs from the drop-down menu.
Chapter 30 Solutions
ORGANIC CHEMISTRY
Ch. 30 - Prob. 30.1PCh. 30 - Prob. 30.2PCh. 30 - Prob. 30.3PCh. 30 - Draw the mechanism for the radical polymerization...Ch. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Prob. 30.8PCh. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12
What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15
What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction.
a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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Similar questions
- Can you explain condensation polymerization and give an example with structure of one with 2 carboxylic acid groups and 2 OH groups.arrow_forwardExplain why styrene (CH2=CHPh) can be polymerized to polystyrene by all three methods of chain-growth polymerization.arrow_forwardPolystyrene results from the polymerization of H H H A. CH=C B. CH₂=C C. CHFC H Multiple Choice O о O O CH 3 I CN H D. CH= C1 H E. CH=Carrow_forward
- Which of the following is the first step in the cationic polymerization of alkenes? Select one: Attack of π-electrons to a proton H+. Reduction of the π-electrons. Elongation of the polymer chain. Attack of π-electrons to a carbocation. Which of the following is FALSE regarding terminal alkynes? Select one: O The proton in the terminal carbon is weakly acidic. They react with H₂O, H₂SO4, HgSO4 to produce an aldehyde. O The hydrohalogenation reaction yields a geminal dihalide. O Treatment with alcoholic AgNO3 produces a silver acetylide.arrow_forwardDraw the structure of the polymer formed from ring-opening metathesis polymerization (ROMP) of each monomer.arrow_forwardKodel is a condensation polymer made from terephthalic acid and 1,4-cyclohexanedimethanol. Write the structure of the resulting polymer.arrow_forward
- Draw the structure for the polymer produced from the monomer vinylidene chloride (CH2=CCl2).arrow_forwardPoly(ethylene terephthalate) (PET) can be prepared by this reaction. Propose a mecha- nism for the step-growth reaction in this polymerization. 275°C n CH;OC- -COCH, + n HOCH,CH,OH -COCH,CH,O- + 2n CH3OH Dimethyl terephthalate Ethylene glycol Poly(ethylene terephthalate) Methanolarrow_forwardNylons are strong sythetic fibers commonly used to make clothing and other goods. One of the most common nylons, Nylon 66, is made by the condensation reaction between adipic acid and hexamethylenediamine (hexane-1,6-diamine). Modify the monomers to create one repeat unit of the polymer. NH Incorrectarrow_forward
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