ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 30, Problem 30.60P
Interpretation Introduction

Interpretation: A structure for the highly cross-linked polymer, obtained from the reaction of urea [(NH2)C=O] with formaldehyde (CH2=O) is to be drawn.

Concept introduction: A thermosetting polymer has complex networks of covalent bonds, due to which it cannot be re-melted to bring in liquid phase. The chemical reaction for the formation of a thermosetting polymer is carried out in the presence of Lewis acid catalyst, which departs small molecules, like H2O as the by-product.

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EVI41 c) Discuss the main purpose of vulcanization of natural rubber AN(4 d) What is a biodegradable polymer? Give an example of a biodegradable aliphatic polyester.
"Co-polymers" consist of two different monomers ("A" and "B") joined in analternating fashion (ABABAB...). Block co-polymers also consist of twodifferent monomers, but in this case, blocks of polymer containing only Aunits are joined to blocks of polymer containing only B units(AAAAABBBBB...). How block co-polymers are synthesized?
The reaction of urea [(NH2)2C = O] and formaldehyde (CH2 = O) forms a highly cross-linked polymer used in foams. Suggest a structure for this polymer. [Hint: Examine the structures of Bakelite (Figure 30.7) and Melmac (Problem 30.58).]Figure 30.7: The synthesis of Bakelite from phenol and formaldehyde

Chapter 30 Solutions

ORGANIC CHEMISTRY

Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12 What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15 What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction. a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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