An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 3.5, Problem 38P

Suppose you have a mixture of gases (such as air, a mixture of nitrogen and oxygen). The mole fraction x i of any species i is defined as the fraction of all the molecules that belong to that species: x i = N i / N t o t a l . The partial pressure P i of species i is then defined as the corresponding fraction of the total pressure: P i = x i P . Assuming that the mixture of gases is ideal, argue of that the chemical potential μ i of species i in this system is the same as if the other gases were not present, at a fixed partial pressure P i .

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An Introduction to Thermal Physics

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