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Chapter 38, Problem 16Q
To determine

The explanation for an increase in separation between energy states with an increase in n but the correspondence principle doesn’t require closer spacing between states as n increases to approach classical situations.

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a) If the electron is in the ground state argue that the expectation value of the electric dipole (P.) =(qf) must vanish. Do not need to do a calculation. b) Show that for some of the n=2 states the expectation value (p,)=(qî) does not vanish. Give one example and proceed to calculate that expectation value.
3. Consider a particle of mass m in the potential V = = Vo[8(x − a) — 8(x+a)]. Show that there is always a bound state for all nonvanishing a.
if the chlorine molecule at 290K were to rotate at the angular frequency predicted by the equipartition theorem what would be the average centipital force ? ( the atoms of Cl are 2 x 10-10 m apart and the mass of the chlorine atom 35.45 a.m.u )
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