CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 4, Problem 67P
Draw the products of combustion of each
a. b.
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1. Provide the IUPAC name.
a.
b.
H3CO.
H₂N
D
O₂N
F
NO2
IUPAC name
IUPAC name
Draw the structure of an alkane that:
a. Contains only 1° and 4° carbons. c. Contains only 1° and 2° hydrogens.
b. Contains only 2° carbons. d. Contains only 1° and 3° hydrogens.
Name each monosubstituted benzene.
CH3
Br
a.
b.
C.
Chapter 4 Solutions
CNCT ORG CHEM 6 2020
Ch. 4.1 - Prob. 1PCh. 4.1 - Problem 4.2 Which of the following is not another...Ch. 4.1 - Problem 4.3 Draw the five constitutional isomers...Ch. 4.1 - Prob. 4PCh. 4.1 - Prob. 5PCh. 4.2 - Draw the five constitutional isomers that have...Ch. 4.4 - Problem 4.7 Give the IUPAC name for each...Ch. 4.4 - Give the IUPAC name for each compound. a....Ch. 4.4 - Problem 4.9 Give the structure corresponding to...Ch. 4.4 - Prob. 10P
Ch. 4.5 - Give the IUPAC name for each compound.Ch. 4.5 - Give the structure corresponding to each IUPAC...Ch. 4.8 - Arrange the following compounds in order of...Ch. 4.9 - Problem 4.14 Draw the staggered and eclipsed...Ch. 4.9 - Prob. 15PCh. 4.9 - Prob. 16PCh. 4.10 - Problem 4.17 a. Draw the three staggered and...Ch. 4.10 - Problem 4.18 Rank the following conformations in...Ch. 4.10 - Problem 4.19 Consider rotation around the...Ch. 4.10 - Calculate the destabilization present in each...Ch. 4.12 - Problem 4.21 Classify the ring carbons as up or...Ch. 4.12 - Problem 4.22 Using the cyclohexane with the C’s...Ch. 4.13 - Draw a second chair conformation for each...Ch. 4.13 - Problem 4.24 Draw both conformations for and...Ch. 4.13 - Problem 4.25 Draw the structure for each compound...Ch. 4.13 - Prob. 26PCh. 4.14 - Prob. 31PCh. 4.14 - Prob. 32PCh. 4.15 - Prob. 33PCh. 4 - Name each alkane using the ball-and-stick model,...Ch. 4 -
4.40 Draw the structure corresponding to each...Ch. 4 - 4.42 Give the IUPAC name for each compound.
a....Ch. 4 - Prob. 42PCh. 4 - 4.46 Considering rotation around the bond...Ch. 4 - 4.50 Calculate the barrier to rotation for each...Ch. 4 - 4.51 The eclipsed conformation of is less...Ch. 4 - (a) Draw the anti and gauche conformations for...Ch. 4 - For each compound drawn below: a.Label each OH,Br...Ch. 4 - Draw the two possible chair conformations for...Ch. 4 - For each compound drawn below: a. Draw...Ch. 4 - Classify each pair of compounds as constitutional...Ch. 4 - Prob. 66PCh. 4 - 4.64 Draw the products of combustion of each...Ch. 4 - 4.65 Hydrocarbons like benzene are metabolized in...Ch. 4 - Prob. 69PCh. 4 - Prob. 70PCh. 4 - Cyclopropane and cyclobutane have similar strain...Ch. 4 - Prob. 72PCh. 4 - Haloethanes (CH3CH2X,X=Cl,Br,I) have similar...Ch. 4 - Prob. 74PCh. 4 - Prob. 75PCh. 4 - Consider the tricyclic structure B (a) Label each...Ch. 4 - Read Appendix B on naming branched alkyl...Ch. 4 - Read Appendix B on naming bicyclic compounds. Then...
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- Draw the structure corresponding to each name. a. propyl formate b. butyl butanoate c. heptyl benzoate d. N-ethylhexanamide e. N-ethyl- N-methylheptanamidearrow_forwardDraw the structure of each isomer.arrow_forward1. a. Draw the structures of the two isomers of dibromoethane. Name them by the IUPAC system. b. Draw out the structures of the two isomers of iodopropane. Name them by the IUPAC system. c. Draw the structures of the three isomers of dichloroethene. Name each one by the IUPAC system, indicating stereochemistry where relevant.arrow_forward
- Draw a complete structure for each alkene or alkyne. a. CH2 CHCH2CH3 b. CH3C CCH2CH3arrow_forwardCompare the boiling point of toluene, cyclohexene, and heptane. Why the molecular mass of toluene is lower than the of heptane, but the boiling point of toluene is higher than heptane? Why cyclohexane are unsaturated but lower boiling point than heptane?arrow_forward8. Name each alkyne. A. CH3CH2CH2C=CH B. CH3CH2CH2C=CCH3arrow_forward
- c. CH2-CH2-CH2-CH-CH3 b. C CH3 CH3 d. CH3-CH2-CH-CH,-CH--CH3 CH3 111s C. CH3 12.36 Give the IUPAC name for each of the follov ing d. alkanes. a. CH3-CH,--CH-CH2-CH,-CH3 ČH3 12.39 b. CH3--CH2-CH2-CH-CH3 ČH3 CH c. CH-CH2-CH-CH3 ČH3 CH3 d. CH3-CH-CH2-CH-CH3 CH3 CH3 14.4 12.37 Give the IUPAC name for each of the followi ng alkanes. a. CH3-CH-CH2-CH-CH-CH3 CH3 CH3 CH3 CH3 b. CH3--C-CH,-CH-CH3 CH3 CH3 12 CH3 c. CH3-CH2-C-CH2-CH3 CH2 CH3 CH3 d. CH3-CH2-C-CH2-CH2 CH3 CH2 1. CH3 12.38 Give the IUPAC name for each of the follo ng alkanes. a. CH3-CH2-CH-CH-CH-CH-C CH3 CH2 CH3 CH3arrow_forwardB) Write a structural formula that corresponds to the molecular formula CH,O and is a. acyclic b. carbocyclic c. heterocyclicarrow_forwardPlease explain the chosen letter. Which is NOT a physical property of alcohols or phenols? a. Phenols are generally only slightly soluble in water. b. The solubilities of normal primary alcohols in water decrease with increasing molecular weight. c. The hydroxyl group of an alcohol is nonpolar. d. Due to hydrogen bonding, boiling points of alcohols are much higher than those of corresponding alkanes.arrow_forward
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