The possible stereoisomers of the given compound has to be drawn. Concept introduction: Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter. Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups. Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

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Answer 1

Question

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Label the two stereogenic centers in each compound and draw all possible stereoisomers.

(a) Locate the stereogenic centers in the ball-and-stick model of ezetimibe (trade name Zetia), a cholesterol-lowering drug. (b) Label each stereogenic center as R or S.

a.Locate the stereogenic centers in the ball-and-stick model of ezetimibe (trade name Zetia), a cholesterol-lowering drug. b. Label each stereogenic center as R or S.

Answer 2

Question

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Answer 3

Question

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Answer 4

Question

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

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Answer 5

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 6

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

Answer 7

Chapter 4, Problem 88P

(a)

Interpretation Introduction

Interpretation:

The possible stereoisomers of the given compound has to be drawn.

Concept introduction:

Stereoisomers are isomers which have different spatial arrangement in spite of same bond connectivity. Stereoisomers are due to the presence of stereocenter.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Fischer projections: the asymmetric center (carbon) represents as the point of intersection of two perpendicular lines, in which the horizontal lines represent the bonds that project out of the plane of the paper and the vertical lines represent the bonds that away from the plane of the paper.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The optically inactive stereoisomers from the above four stereoisomers of the given compound has to be determined.

Concept introduction:

Optical activity of a molecule is the interaction between molecule and plane-polarized light.

Molecule having asymmetric center shows optical activity except mesocompounds.

Asymmetric center is a stereocenter which arises to hydrocarbons if the carbon is bonded to four different groups.

Mesocompounds has asymmetric centers and a plane of symmetry, so the molecule superimposable on its mirror image, thereby the compound is achiral.

If the four groups attached to both asymmetric centers of a compound are identical, then the compound is a mesocompound.

Answer 10

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Answer 12

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Answer 13

Ch. 4.1 - Prob. 2P Ch. 4.1 - Prob. 3P Ch. 4.1 - Prob. 4P Ch. 4.1 - Prob. 5P Ch. 4.1 - Which of the roll owing compounds have a dipole...Ch. 4.2 - Draw and label the E and Z isomers for each of the...Ch. 4.2 - Assign relative priorities to each set of...Ch. 4.2 - Tamoxifen slows the growth of some breast tumors...Ch. 4.2 - Prob. 10P Ch. 4.2 - Name each of the following:

Solution Summary: The author explains that stereoisomers have different spatial arrangement in spite of same bond connectivity. Asymmetric centers arise to hydrocarbons if the carbon is bonded to four different groups.

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