Intro Spectroscopy
5th Edition
ISBN: 9781305221796
Author: PAVIA
Publisher: Cengage
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The 10-fold X-ray reduction values for (a) water, (b) concreate, (c) iron and (d) lead are equal 100 cm, 20 cm, 10 cm and 5 cm, respectively. Find corresponding values of linear attenuation coefficients.
However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be
A = 0.82i + 0.99j + 0.84k
B = 1.09i + -1.01j + -0.97k
What is the angle (in degrees) between the bonds based on this new data?
Inert concentration in germanium semiconductor material at T=400K(x10^14 per cm^3)?
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- The fundamental frequency is 2230 cm−1 for the molecule 1H127I. If the H atom is replacedwith D (an isotope of H atom with mass 2, i.e. 2H), calculate the fundamental frequency assumingthat the force constant stays the same. Repeat the calculation if the diatomic molecule underconsideration is 1H37Cl (fundamental frequency = 2886 cm−1). Explain your observations.arrow_forwardThe rotational constant of 12C160 2 (from Raman spectroscopy) is 11.70 GHz. What is the CO bond length in themolecule?arrow_forwardCalculate the number of Frenkel defects per cubic meter in potassium chlorideat 500degC. The energy required to form each Frenkeldefect is 2.6 eV, whereasthe density for KCl is 1.955 g/cm3.arrow_forward
- According to a new spectroscopy analysis, the adjacent bond vectors was found to be A = 1.07i + 0.83j + 0.81k B = 1.03i + -0.99j + -0.85k What is the angle (in degrees) between the bonds based on this new data?arrow_forwardTo obtain the most precise value of BE from the equation BE=[ZM(1H)+ Nmn]c2 − m(AX)c2 , we should take into account the binding energy of the electrons in the neutral atoms. Will doing this produce a larger or smaller value for BE? Why is this effect usually negligible?arrow_forwardConsider a p+-n Si diode with NA = 1018 cm-3 and ND = 1016 cm-3. The hole diffusion coefficient in the n-side is 10 cm2/s and carrier lifetime τp =10-7 s. The device area is 10-4 cm2. Calculate the reverse saturation current and the forward current at a forward bias of 0.7 V at 300 K.arrow_forward
- Consider a p+ -n Si diode with NA = 1018 cm -3 and ND = 1016 cm -3 . The hole diffusion coefficient in the n-side is 10 cm2 /s and carrier lifetime τp =10-7 s. The device area is 10-4 cm2 . Calculate the reverse saturation current and the forward current at a forward bias of 0.7 V at 300 K.arrow_forwardThe measured density of a KCl crystal is 1.984 g/cm3. What is the equilibrium separation distance of K+ and Cl- ions?arrow_forwardThe measured density of a CsCl crystal is 3.988 g/cm3. What is the equilibrium separate distance of Cs+ and Cl- ions?arrow_forward
- Consider spherical nanoparticles of copper with diameters of 10 and 100 nm. A) Calculate the total number of atoms in the particles,considering the lattice parameter of bulk Cu. B) Calculate the number of atoms at the grain boundaries for a typical grain boundary thickness of 1nm.arrow_forwardIf a pentavalent element like antimony is doped to an extent of 1 atom in 10^8 germanium atoms what will be the conductivity after doping? (Concentration of germanium atoms in given sample is calculated as 4.41*10^28/m^3; consider the mobility of electron and hole as 0.38 and 0.18m^2/V.s, respectively)arrow_forwardThe first three absorption lines in the pure rotational spectrum of gaseous 12C16O are found to have the frequencies 1.15 × 1011, 2.30 × 1011, and 3.46 × 1011 s21. Calculate:(a) The moment of inertia I of CO (in kg m2)(b) The energies of the J 5 1, J 5 2, and J 5 3 rotational levels of CO, measured from the J 5 0 state (in joules)(c) The CUO bond length (in angstroms)arrow_forward
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