Introduction To Quantum Mechanics
Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 4.1, Problem 4.7P
To determine

The spherical harmonics Yll(θ,ϕ) and Y32(θ,ϕ) and whether they satisfy the angular equation for appropriate value of m and l.

Expert Solution & Answer
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Answer to Problem 4.7P

The spherical harmonics Yll(θ,ϕ) is 1l!(2l+1)!4π(12eiϕsinθ)l_ and Y32(θ,ϕ) is 141052πe2iϕsin2θcosθ_ and it satisfies with the angular equation for appropriate value of m and l.

Explanation of Solution

Write the general expression for the spherical harmonics Yll(θ,ϕ).

    Yll(θ,ϕ)=(2l+1)4π1(2l)!eilϕPll(cosθ)        (I)

Here, Pll(cosθ) is the associated Legendre function.

Write the expression for the associated Legendre function.

    Pll(x)=(1)l(1x2)l/2(ddx)lPl(x)        (II)

Here, Pl(x) is the Legendre function.

Write the expression for the Legendre function.

    Pl(x)=12ll!(ddx)l(x21)l        (III)

Use equation (III) in (II) to solve for Pll(x).

    Pll(x)=(1)l2ll!(1x2)l/2(ddx)2l(x21)l        (IV)

The (x21)l=x2l+, where all other terms involve powers of x less than 2l, and hence give zero when differentiated 2l times.

Then the equation (IV) becomes,

    Pll(x)=(1)l2ll!(1x2)l/2(ddx)2lx2l        (V)

The expansion of (ddx)nxn can be written as

    (ddx)nxn=n!        (VI)

Use equation (VI) in (V) and it becomes,

    Pll(x)=(1)l(2l)!2ll!(1x2)l/2        (VII)

Use equation (VII) in (I) to solve for the spherical harmonics Yll(θ,ϕ).

    Yll(θ,ϕ)=(1)l(2l+1)!4πeilϕ(2l)!2ll!(sinθ)l=1l!(2l+1)!4π(12eiϕsinθ)l        (VIII)

Use equation (VIII) to find Y32(θ,ϕ).

    Y32(θ,ϕ)=74π15!e2iϕP32(cosθ)=74π15!15e2iϕcosθsin2θ=141052πe2iϕsin2θcosθ        (IX)

Consider 1l!(2l+1)!4π(12)l=A and the spherical harmonics Yll(θ,ϕ) can be written as

    Yll(θ,ϕ)=A(eiϕsinθ)l        (X)

Differentiate equation (X) with respect to θ and it becomes,

    Yllθ=Aeilϕl(sinθ)l1cosθsinθYllθ=AeilϕlcosθYllsinθθ(sinθYllθ)=lcos(sinθYllθ)lsin2θYll=(l2cos2θlsin2θ)Yll        (XI)

Take the second derivative of Yll(θ,ϕ) with respect to ϕ and it becomes,

    2Yllϕ2=l2Yll        (XII)

The sum of the equations (XII) and (XI) can be written as

    sinθθ(sinθYllθ)+2Yllϕ2=(l2cos2θlsin2θ)Ylll2Yll=l(l+1)sin2θYll        (XIII)

The equation (XIII) satisfies with the equation given in (4.18).

Consider B=141052π and the spherical harmonics Y32(θ,ϕ) can be written as

    Y32=Be2iϕsin2θcosθ        (XIV)

Take the partial derivative of equation (XIV) with respect to θ and it becomes,

    Y32θ=Be2iϕ(2sinθcos2θsin2θ)        (XV)

Use equation (XV) in (XIII) and it can be written as

    sinθθ(sinθY32θ)=Be2iϕsinθθ(2sin2θcos2θsin4θ)=Be2iϕsinθ(4sinθcos2θ4sin3θ4sin3θcosθ)=4Be2iϕsin2θcosθ(cos2θ2sin2θ)=4(cos22sin2θ)Y32        (XVI)

Take the second partial derivative of Y32 with respect to ϕ.

    2Y32ϕ2=4Y32        (XVII)

Use equation (XVII) and (XVI) in (XIII) and compare,

    4(cos2θ2sin2θ1)Y32=4(3sin2θ)Y32=l(l+1)sin2θY32        (XVIII)

In equation (XVIII), where l=3 fits the RHS of equation 4.18 and hence it is proved.

Conclusion:

Therefore, The spherical harmonics Yll(θ,ϕ) is 1l!(2l+1)!4π(12eiϕsinθ)l_ and Y32(θ,ϕ) is 141052πe2iϕsin2θcosθ_ and it satisfies with the angular equation for appropriate value of m and l.

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