What reagent solution might you use to separate the cations the following matures, that is, with one in appearing in solution and the otherin a precipitate? (Hint: Refer to Table 5.1, and consider water also to a reagent.)
a.
b.
a.
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General Chemistry: Principles and Modern Applications (11th Edition)
- A 100.0-mL aliquot of 0.200 M aqueous potassium hydroxide is mixed with 100.0 mL of 0.200 M aqueous magnesium nitrate. a. Write a balanced chemical equation for any reaction that occurs. b. What precipitate forms? c. What mass of precipitate is produced? d. Calculate the concentration of each ion remaining in solution after precipitation is complete.arrow_forwardAn aqueous sample is known to contain either Ag+ or Mg2+ ions. Treatment of the sample with NaOH produces a precipitate, but treatment with KBr does not. Use the solubility rules (see Table 4.1) to determine which cation is present. TABLE 4.1 Solubility Rules for Ionic Compounds in Waterarrow_forward42. a. Fill in the following table as if it is a well plate and you are mixing two aqueous compounds at a time to see if a precipitate forms. If a precipitate is expected to form, indicate that by writing the correct formula for the precipitate in the corresponding box in the table. If no precipitate is expected to form, write “NO” in the box. CaCI2 Pb(NO3)2 (NH4)3PO4 Na2CO3 AgNO3 K2SO4 b. How do you prepare 300.0 mL of a 0.250 M CaCl2 solution using an available 2(X) M solution? Support your answer with calculations, but also make sure you describe how to prepare the solution.arrow_forward
- Separate samples of a solution of an unknown soluble ionic compound are treated with KCl, Na2SO4, and NaOH. A precipitate forms only when Na2SO4 is added. Which cations could be present in the unknown soluble ionic compound?arrow_forwardLead(II) nitrate is added to four separate beakers that contain the following: aker 1 (sodium chloride) eaker 2 (sodium hydroxide) eaker 3 (sodium phosphate) eaker 4 (sodium sulfate) ter the addition of the lead(II) nitrate solution to each beaker, in which beaker(s) will a precipitate form? Use the general solubility rules given in Table 7.1 to guide you.arrow_forwardAn aqueous sample is known to contain either Pb2+ or Ba2+. Treatment of the sample with NaCl produces a precipitate. Use the solubility rules (see Table 4.1) to determine which cation is present. TABLE 4.1 Solubility Rules for Ionic Compounds in Waterarrow_forward
- One method for determining the purity of aspirin (C9H8O4) is to hydrolyze it with NaOH solution and then to titrate the remaining NaOH. The reaction of aspirin with NaOH is as follows: A sample of aspirin with a mass of 1.427 g was boiled in 50.00 mL of 0.500 M NaOH. After the solution was cooled, it took 31.92 mL of 0.289 M HCl to titrate the excess NaOH. Calculate the purity of the aspirin. What indicator should be used for this titration? Why?arrow_forward68. Aluminum ion may be precipitated from aqueous solution by addition of hydroxide ion, forming Al(OH)3. A large excess of hydroxide ion must not be added, however, because the precipitate of Al(OH)3 will redissolve as a soluble compound containing aluminum ions and hydroxide ions begins to form. How many grains of solid NaOH should be added to 10.0 mL of 0.250 M A1Cl3 to just precipitate all the aluminum?arrow_forwardThere are many ionic compounds that dissolve in water to a very small extent. One example is lead(II) chloride. When it dissolves an equilibrium is established between the solid salt and its component ions. Suppose you stir some solid PbCl2 into water. Explain how you would prove that the compound dissolves but to a small extent? Is the dissolving process product-favored or reactant-favored? pbcl2(s)pb2+(aq)+2cl(aq)arrow_forward
- A sample of solid calcium hydroxide, Ca(OH)2, is allowed to stand in water until a saturated solution is formed. A titration of 75.00 mL of this solution with 5.00102M HCl requires 36.6 mL of the acid to reach the end point. Ca(OH)2(aq)+2HCl(aq)CaCl2(aq)+2H2O(l) What is the molarity?arrow_forwardTwenty-five milliliters of a solution (d=1.107g/mL)containing 15.25% by mass of sulfuric acid is added to 50.0 mL of 2.45 M barium chloride. (a) What is the expected precipitate? (b) How many grams of precipitate are obtained? (c) What is the chloride concentration after precipitation is complete?arrow_forward
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