Concept explainers
(a)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of
Answer to Problem 5.11P
The priority of ethyl group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. In methyl group
The higher priority is given to ethyl group
(b)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
Answer to Problem 5.11P
The higher priority is given to group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. The atomic number of Iodine group
The higher priority is given to group
(c)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
Answer to Problem 5.11P
The higher priority is given to group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
The mass number of group
The higher priority is given to group
(d)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
Answer to Problem 5.11P
The higher priority is given to group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority.
In group
The higher priority is given to group
(e)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
Answer to Problem 5.11P
The higher priority is given to group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority.
The second carbon atom of group
The higher priority is given to group
(f)
Interpretation: The group with higher priority from the given pair is to be identified.
Concept introduction: The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority. However, in case of isotopes, the atomic number is same but the mass number is different. The isotope with higher mass number is given higher priority.
Answer to Problem 5.11P
The higher priority is given to group
Explanation of Solution
The groups are prioritized on the basis of atomic number of their atoms. The group that contain atom with higher atomic number is given higher priority.
The carbon atom of group
The higher priority is given to group
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Chapter 5 Solutions
ORGANIC CHEMISTRY (LOOSELEAF) >CUSTOM<
- Rank the following groups in order of decreasing priority. a. – COOH, – H, – NH2, – OH b. – H, – CH3, – Cl, – CH2CI c. -CH2CH3, -CH3, -H, -CH(CH3)2 d. – CH = CH2, – CH3, – C ≡ CH, – Harrow_forwardRank the following groups in order of decreasing priority. −CH=CH2, −CH3, −C≡CH, −Harrow_forwardAssign a priority order (from least to highest priority) to each of the following sets of groups: I. -OCH II. -NH(CH3)2 III. CH2NH2 IV. -OH A. IV, I, III, II B. III, II, IV, I C. II, III, IV, I D. III, IV, I, IIarrow_forward
- Arrange each set in order of decreasing priority using Cahn-Ingold-Prelog priority rules (1 for highest priority). d) _____-Cl, _____-OH, _____-H, _____-NH2 e) _____–CO2CH3, _____-CO2H, _____-OH, _____-OCH3arrow_forwardRank the following groups in order of decreasing priority. −F, −NH2, −CH3, −OHarrow_forwardWhen determining R AND S rank these groups from highest to lowest priorityarrow_forward
- A)Circle all of the stereo centers in MDMA. B) assign the absolute stereochemistry (R or S) for each stereo centerarrow_forwardAssign a priority order (from least to highest priority) to each of the folliowing sets of groups: I. -CH(CH3)2 II. -CH3 III. -H IV. -NH2 A. III, IV, II, I B. IV, I, III, II C. III, II, IV, I D. III, II, I, IVarrow_forwardOrder the following substituents from highest priority to lowest priority: CH3, OH, H,F. Use the Cahn-Ingold-Prelog priority system. a. F, CH3, OH, H b. H, CH3, F, OH c. F, OH, CH3, H d. H, CH3, OH, Farrow_forward
- How to get the wt. sample, g.arrow_forwardFocus only on carbon 1 For carbon 1, which group has the highest priority? a,b,c or d?why? What enantiomer is carbon 1? R or S?arrow_forwardRank the following groups in order of decreasing priority according to the Cahn-Ingold-Prelog system. I) -CH=CH2 II) -CH3 III) -CH IV) -OH 1) IV > III > I > II 2) IV > I > III > II 3) III > IV > I > II 4) II > I > III > IVarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning