ORGANIC CHEM LL W/WILEYPLUS BLCKBRD >I
12th Edition
ISBN: 9781119238249
Author: Solomons
Publisher: WILEY
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Chapter 5, Problem 51P
(Use models co solve this problem.) Write conformational structures for all of the stereoisomers of 1,3-diethylcyclohexane. Label pairs of enantiomers and meso compounds if they exist.
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3)- Determine the total number of conformers and draw the Chair Structures of the conformers for the Tri-substituted
cyclohexane structure given below (i.e., "A"). Draw the relative energy diagram for the possible conformers for the
cyclohexane structure below. Note, draw only the required structures for the conformers of A. Also, include
hydrogen atoms wherever there are substituents on all of your chair conformers.
Answer (Total #of Conformers):
Chair Structures:
Relative Energy Diagram
8 bas roll
3
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Chapter 5 Solutions
ORGANIC CHEM LL W/WILEYPLUS BLCKBRD >I
Ch. 5 - Prob. 1PPCh. 5 - Prob. 2PPCh. 5 - Prob. 3PPCh. 5 - Prob. 4PPCh. 5 - Prob. 5PPCh. 5 - Prob. 6PPCh. 5 - Prob. 7PPCh. 5 - Practice Problem 5.8 Write three-dimensional...Ch. 5 - Prob. 9PPCh. 5 - Prob. 10PP
Ch. 5 - Practice Problem 5.11 List the substituents in...Ch. 5 - Prob. 12PPCh. 5 - Practice Problem 5.13 Tell whether the two...Ch. 5 - Prob. 14PPCh. 5 - Prob. 15PPCh. 5 - Prob. 16PPCh. 5 - Prob. 17PPCh. 5 - Prob. 18PPCh. 5 - Prob. 19PPCh. 5 - Prob. 20PPCh. 5 - Practice Problem 5.21 The following are formulas...Ch. 5 - Practice Problem 5.22 Write three-dimensional...Ch. 5 - Prob. 23PPCh. 5 - Practice Problem 5.24 Give names chat include (R)...Ch. 5 - Prob. 25PPCh. 5 - Prob. 26PPCh. 5 - Prob. 27PPCh. 5 - Prob. 28PPCh. 5 - Practice Problem 5.29 Write formulas for all of...Ch. 5 - Prob. 30PPCh. 5 - Prob. 31PPCh. 5 - Prob. 32PPCh. 5 - Prob. 33PCh. 5 - Prob. 34PCh. 5 - 5.35 Designate the (R) or (S) configuration at...Ch. 5 - Prob. 36PCh. 5 - (a) Write the structure of...Ch. 5 - Shown below are Newman projection formulas for...Ch. 5 - 5.39 Write appropriate structural formulas...Ch. 5 - Discuss whether each of the following compounds...Ch. 5 - Prob. 42PCh. 5 - Prob. 43PCh. 5 - Compound F has the molecular formula C5H8 and is...Ch. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - For the following molecule, draw its enantiomer as...Ch. 5 - 5.49 (Use models to solve this...Ch. 5 - 5.50 (Use models to solve this...Ch. 5 - (Use models co solve this problem.) Write...Ch. 5 - 5.52 Tartaric acid was an important compound in...Ch. 5 - Prob. 53PCh. 5 - Prob. 54PCh. 5 - Prob. 55PCh. 5 - Prob. 1LGPCh. 5 - Prob. 2LGPCh. 5 - Prob. 3LGP
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- I don't understand why the first one and second one are cis and trans respectively. Wouldn't the first one be trans-1,2-dimethylcyclobutane because the torsional strain wouldn't allow the carbons to be in the same conformation. Meaning one of the carbons would be up and then the next would be down and so on. Since both methyl groups are equatorial and the first and second carbons are arranged up and down, wouldn't it be trans. Same logic for the second molecule. Carbon 1, which is attached to the methyl is down, carbon 3 which is attached to the methyl should be down also because of torsional strain, and since both methyl are in axial (or equatorial?), it would be cis. Or is it based off of the way the carbons are positioned in the picture?arrow_forwardSee attached question.arrow_forwardWhich of the following compounds contain stereocenters? Also, what are stereocenters?arrow_forward
- Draw a structural formula and Draw the structure of a compound that is a stereoisomerarrow_forwardWhat is the most stable conformation for trans-1,2-dichlorocyclohexane. Describe and explain brieflyarrow_forwardQ2. Answer any TWO of the following parts: (a) Draw the two main conformations that exist for cyclohexane. Explain clearly why one conformer is more stable than the other. Using cis-1-ethyl-3-methylcyclohexane, as an example, explain how ring flipping occurs. Draw both conformers of cis-1-ethyl-3-methylcyclohexane and explain clearly which one predominates. (b) What is polarimetry? The specific rotation of (R)-carvone is - 61°. A chemist prepared a 750 mg mixture of (R)-carvone and its enantiomer in 10 ml of ethanol and placed the solution in a 10 cm polarimeter cell. The observed rotation was - 4.125°. Calculate the specific rotation for the above mixture. What is meant by enantiomeric excess? Then determine the % enantiomeric excess (% ee) in the mixture. (i) (ii) (iii) What % of the mixture is (R)-carvone and (S)-carvone?arrow_forward
- Question 13 The most stable conformation of line structure X is но ÕH ****** Bu Et H Bu H. Bu Me H 'Bu! Bu HO H OH 'Bu H Et FOH HO OH Ét Me H HO H ÓH I HPOH Ét H OH ÓH Et Me VI II IV V O IV O V None of the given optionsarrow_forwardHow do you account for the difference in energies between the two staggered conformations of 1,2-dichloroethane? How about for the two eclipsed conformations? Draw all four conformations and, on your drawing, indicate sources of strain – torsional, steric (gauche), steric eclipsed.arrow_forwardPlease complete the following related questions i) Draw all possible isomers for the chemical formula Ma3bcd.How many are there in total? How many pairs of enantiomers are there?ii) Repeat for formula Ma3b2c.arrow_forward
- Please help, will provide helpful ratings for correct soln. Thankuarrow_forward10. Provide a structure of an isomer that has the molecular formula C5H8O2 and fits the criteria described below. Note that all of the structures must be neutral and not have any formal charges on any of the atoms. a) Contains an ester and an alkene b) A chiral compound that contains a ring, ether and ketone. c) Contains an alcohol and an alkyne. d) A meso compound that contains two alcohols.arrow_forward1: Draw the chain conformer of... 1a. Cyclohexane, label all the axial and equatorial hydrogens 1b. The most stable conformer of ethylcyclohexane 1c. The most sable conformer of trans-1-tert-butyl-3-methylcyclohexanearrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License