Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Textbook Question
Chapter 5, Problem 5.42QE
The combustion of 1.00 mol liquid methyl alcohol (CH3OH) in excess oxygen is exothermic, giving 727 kJ of heat.
- (a) Write the thermochemical equation for this reaction.
- (b) Calculate the enthalpy change that accompanies the burning 10.0 g methanol.
- (c) Compare this with the amount of heat produced by 10.0 g octane, C8H18, a component of gasoline (see Exercise 5.41).
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Chemistry: Principles and Practice
Ch. 5 - Why must the physical states of all reactants and...Ch. 5 - Why is chemical energy classified as a form of...Ch. 5 - What is the difference between the enthalpy of...Ch. 5 - Classify each process as exothermic or...Ch. 5 - Explain why the specific heat of the contents of...Ch. 5 - Prob. 5.6QECh. 5 - Define heat. What are its units? How does it...Ch. 5 - Prob. 5.8QECh. 5 - Prob. 5.9QECh. 5 - Prob. 5.10QE
Ch. 5 - Prob. 5.11QECh. 5 - Is the Sun exothermic or endothermic? Is it any...Ch. 5 - Under what circumstances is the heat of a process...Ch. 5 - Prob. 5.14QECh. 5 - Prob. 5.15QECh. 5 - Prob. 5.16QECh. 5 - Prob. 5.17QECh. 5 - Prob. 5.18QECh. 5 - Prob. 5.19QECh. 5 - Prob. 5.20QECh. 5 - Prob. 5.21QECh. 5 - Prob. 5.22QECh. 5 - Prob. 5.23QECh. 5 - Prob. 5.24QECh. 5 - Prob. 5.25QECh. 5 - Prob. 5.26QECh. 5 - Prob. 5.27QECh. 5 - Prob. 5.28QECh. 5 - Prob. 5.29QECh. 5 - Prob. 5.30QECh. 5 - Prob. 5.31QECh. 5 - A chemical reaction occurs and absorbs 64.7 cal....Ch. 5 - The enthalpy change for the following reaction is...Ch. 5 - Prob. 5.34QECh. 5 - The thermochemical equation for the burning of...Ch. 5 - When lightning strikes, the energy can force...Ch. 5 - One step in the manufacturing of sulfuric acid is...Ch. 5 - If nitric acid were sufficiently heated, it can be...Ch. 5 - Prob. 5.39QECh. 5 - Prob. 5.40QECh. 5 - Prob. 5.41QECh. 5 - The combustion of 1.00 mol liquid methyl alcohol...Ch. 5 - Another reaction that is used to propel rockets is...Ch. 5 - Prob. 5.44QECh. 5 - Prob. 5.45QECh. 5 - Prob. 5.46QECh. 5 - Prob. 5.47QECh. 5 - Prob. 5.48QECh. 5 - Prob. 5.49QECh. 5 - Prob. 5.50QECh. 5 - The enthalpy change when 1 mol methane (CH4) is...Ch. 5 - Prob. 5.52QECh. 5 - Prob. 5.53QECh. 5 - How much energy is required to raise the...Ch. 5 - How much heat, in kilojoules, must be removed to...Ch. 5 - Prob. 5.56QECh. 5 - Prob. 5.57QECh. 5 - Prob. 5.58QECh. 5 - Prob. 5.59QECh. 5 - Prob. 5.60QECh. 5 - When 7.11 g NH4NO3 is added to 100 mL water, the...Ch. 5 - A 50-mL solution of a dilute AgNO3 solution is...Ch. 5 - A 0.470-g sample of magnesium reacts with 200 g...Ch. 5 - Dissolving 6.00 g CaCl2 in 300 mL of water causes...Ch. 5 - Draw an energy-level diagram (e.g., see Figure...Ch. 5 - Prob. 5.66QECh. 5 - Prob. 5.67QECh. 5 - Prob. 5.68QECh. 5 - Calculate H for the reaction...Ch. 5 - Prob. 5.70QECh. 5 - Given the thermochemical equations...Ch. 5 - In the process of isolating iron from its ores,...Ch. 5 - Prob. 5.73QECh. 5 - Prob. 5.75QECh. 5 - Prob. 5.77QECh. 5 - Prob. 5.78QECh. 5 - Prob. 5.79QECh. 5 - Prob. 5.80QECh. 5 - Prob. 5.81QECh. 5 - Prob. 5.82QECh. 5 - Calculate H when a 38-g sample of glucose,...Ch. 5 - Prob. 5.84QECh. 5 - The octane number of gasoline is based on a...Ch. 5 - One of the components of jet engine fuel is...Ch. 5 - Prob. 5.87QECh. 5 - Prob. 5.88QECh. 5 - When a 2.30-g sample of magnesium dissolves in...Ch. 5 - Prob. 5.90QECh. 5 - Prob. 5.91QECh. 5 - What mass of acetylene, C2H2(g), must be burned to...Ch. 5 - It takes 677 J of heat to increase the temperature...Ch. 5 - Prob. 5.94QECh. 5 - Prob. 5.96QECh. 5 - The enthalpy of combustion of liquid n-hexane,...Ch. 5 - What is Hrxn for reaction of iron(III) oxide and...Ch. 5 - Prob. 5.99QECh. 5 - Prob. 5.100QECh. 5 - In the 1880s, Frederick Trouton noted that the...Ch. 5 - Prob. 5.102QECh. 5 - Prob. 5.103QECh. 5 - Prob. 5.104QECh. 5 - Prob. 5.105QECh. 5 - A compound is 82.7% carbon and 17.3% hydrogen, and...Ch. 5 - Prob. 5.107QECh. 5 - Prob. 5.108QE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- When 2.50 g of methane burns in oxygen, 125 kJ of heat is produced. What is the enthalpy of combustion per mole of methane under these conditions?arrow_forwardWhat mass of acetylene, C2H2(g), must be burned to produce 3420 kJ of heat, given that its enthalpy of combustion is 1301 kJ/mol? Compare this with the answer to Exercise 5.91 and determine which substance produces more heat per gram.arrow_forwardWhen one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon tetrafluoride gases are formed and 2496.7 kJ of heat are given off. What is Hf for CF4(g)?arrow_forward
- How much heat is absorbed by a 44.7-g piece of leadwhen its temperature increases by 65.4°C?arrow_forwardCompounds with carboncarbon double bonds, such as ethylene, C2H4, add hydrogen in a reaction called hydrogenation. C2H4(g)+H2(g)C2H6(g) Calculate the enthalpy change for this reaction, using the following combustion data: C2H4(g)+3O2(g)2CO2(g)+2H2O(l);H=1411kJC2H6(g)+72O2(g)2CO2(g)+3H2O(l);H=1560kJH2(g)+12O2(g)H2O(l);H=286kJarrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forward
- Although the gas used in an oxyacetylene torch (Figure 5.7) is essentially pure acetylene, the heat produced by combustion of one mole of acetylene in such a torch is likely not equal to the enthalpy of combustion of acetylene listed in Table 5.2. Considering the conditions for which the tabulated data are reported, suggest an explanation.arrow_forwardWhen one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?arrow_forwardA 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.arrow_forward
- One step in the manufacturing of sulfuric acid is the conversion of SO2(g) to SO3(g). The thermochemical equation for this process is SO2(g)+12O2(g)SO3(g)H=98.9kJ The second step combines the SO3 with H2O to make H2SO4. (a) Calculate the enthalpy change that accompanies the reaction to make 1.00 kg SO3(g). (b) Is heat absorbed or released in this process?arrow_forwardSalicylic acid, C7H6O3, is one of the starting materials in the manufacture of aspirin. When 1.00 g of salicylic acid burns in a bomb calorimeter, the temperature of the bomb and water goes from 23.11C to 28.91C. The calorimeter and water absorb 21.9 kJ of heat. How much heat is given off when one mole of salicylic acid burns?arrow_forward
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