CHEM:ATOM FOC 2E CL (TEXT)
2nd Edition
ISBN: 9780393284218
Author: Stacey Lowery Bretz, Natalie Foster, Thomas R. Gilbert, Rein V. Kirss
Publisher: WW Norton & Co
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Which of the molecular orbitals below is the LUMO for the diatomic molecule O₂?
The default font in Moodle does not display lower case Greek letters well. The symbol that looks like this (π) is pi (π).
Select one:
02s
O
*
120
020
112p
*
025
*
02P
Would this be an aaceptable model for the hybridized orbitals for H2N2? Where does the lone pair go in the physical representation?
In the molecule HCN, how many unhybridized p orbitals
are there for the C and N atoms?
O
1 unhybridized orbital in C; 2 unhybridized orbitals in
N
O
1 unhybridized orbital in C; 1 unhybridized orbital in
N
O
2 unhybridized orbitals in C; 1 unhybridized orbital in
N
3 unhybridized orbitals in C; 3 unhybridized orbitals
in N
O
2 unhybridized orbitals in C; 2 unhybridized orbitals
in N
Chapter 5 Solutions
CHEM:ATOM FOC 2E CL (TEXT)
Ch. 5 - Prob. 5.1VPCh. 5 - Prob. 5.2VPCh. 5 - Prob. 5.3VPCh. 5 - Prob. 5.4VPCh. 5 - Prob. 5.5VPCh. 5 - Prob. 5.6VPCh. 5 - Prob. 5.7VPCh. 5 - Prob. 5.8VPCh. 5 - Prob. 5.9VPCh. 5 - Prob. 5.10VP
Ch. 5 - Prob. 5.11QACh. 5 - Prob. 5.12QACh. 5 - Prob. 5.13QACh. 5 - Prob. 5.14QACh. 5 - Prob. 5.15QACh. 5 - Prob. 5.16QACh. 5 - Prob. 5.17QACh. 5 - Prob. 5.18QACh. 5 - Prob. 5.19QACh. 5 - Prob. 5.20QACh. 5 - Prob. 5.21QACh. 5 - Prob. 5.22QACh. 5 - Prob. 5.23QACh. 5 - Prob. 5.24QACh. 5 - Prob. 5.25QACh. 5 - Prob. 5.26QACh. 5 - Prob. 5.27QACh. 5 - Prob. 5.28QACh. 5 - Prob. 5.29QACh. 5 - Prob. 5.30QACh. 5 - Prob. 5.31QACh. 5 - Prob. 5.32QACh. 5 - Prob. 5.33QACh. 5 - Prob. 5.34QACh. 5 - Prob. 5.35QACh. 5 - Prob. 5.36QACh. 5 - Prob. 5.37QACh. 5 - Prob. 5.38QACh. 5 - Prob. 5.39QACh. 5 - Prob. 5.40QACh. 5 - Prob. 5.41QACh. 5 - Prob. 5.42QACh. 5 - Prob. 5.43QACh. 5 - Prob. 5.44QACh. 5 - Prob. 5.45QACh. 5 - Prob. 5.46QACh. 5 - Prob. 5.47QACh. 5 - Prob. 5.48QACh. 5 - Prob. 5.49QACh. 5 - Prob. 5.50QACh. 5 - Prob. 5.51QACh. 5 - Prob. 5.52QACh. 5 - Prob. 5.53QACh. 5 - Prob. 5.54QACh. 5 - Prob. 5.55QACh. 5 - Prob. 5.56QACh. 5 - Prob. 5.57QACh. 5 - Prob. 5.58QACh. 5 - Prob. 5.59QACh. 5 - Prob. 5.60QACh. 5 - Prob. 5.61QACh. 5 - Prob. 5.62QACh. 5 - Prob. 5.63QACh. 5 - Prob. 5.64QACh. 5 - Prob. 5.65QACh. 5 - Prob. 5.66QACh. 5 - Prob. 5.67QACh. 5 - Prob. 5.68QACh. 5 - Prob. 5.69QACh. 5 - Prob. 5.70QACh. 5 - Prob. 5.71QACh. 5 - Prob. 5.72QACh. 5 - Prob. 5.73QACh. 5 - Prob. 5.74QACh. 5 - Prob. 5.75QACh. 5 - Prob. 5.76QACh. 5 - Prob. 5.77QACh. 5 - Prob. 5.78QACh. 5 - Prob. 5.79QACh. 5 - Prob. 5.80QACh. 5 - Prob. 5.81QACh. 5 - Prob. 5.82QACh. 5 - Prob. 5.83QACh. 5 - Prob. 5.84QACh. 5 - Prob. 5.85QACh. 5 - Prob. 5.86QACh. 5 - Prob. 5.87QACh. 5 - Prob. 5.88QACh. 5 - Prob. 5.89QACh. 5 - Prob. 5.90QACh. 5 - Prob. 5.91QACh. 5 - Prob. 5.92QACh. 5 - Prob. 5.93QACh. 5 - Prob. 5.94QACh. 5 - Prob. 5.95QACh. 5 - Prob. 5.96QACh. 5 - Prob. 5.97QACh. 5 - Prob. 5.98QACh. 5 - Prob. 5.99QACh. 5 - Prob. 5.100QACh. 5 - Prob. 5.101QACh. 5 - Prob. 5.102QACh. 5 - Prob. 5.103QACh. 5 - Prob. 5.104QACh. 5 - Prob. 5.105QACh. 5 - Prob. 5.106QACh. 5 - Prob. 5.107QACh. 5 - Prob. 5.108QACh. 5 - Prob. 5.109QACh. 5 - Prob. 5.110QACh. 5 - Prob. 5.111QACh. 5 - Prob. 5.112QACh. 5 - Prob. 5.113QACh. 5 - Prob. 5.114QACh. 5 - Prob. 5.115QACh. 5 - Prob. 5.116QACh. 5 - Prob. 5.117QACh. 5 - Prob. 5.118QACh. 5 - Prob. 5.119QACh. 5 - Prob. 5.120QACh. 5 - Prob. 5.121QACh. 5 - Prob. 5.122QACh. 5 - Prob. 5.123QACh. 5 - Prob. 5.124QACh. 5 - Prob. 5.125QACh. 5 - Prob. 5.126QACh. 5 - Prob. 5.127QACh. 5 - Prob. 5.128QACh. 5 - Prob. 5.129QACh. 5 - Prob. 5.130QACh. 5 - Prob. 5.131QACh. 5 - Prob. 5.132QACh. 5 - Prob. 5.133QACh. 5 - Prob. 5.134QACh. 5 - Prob. 5.135QACh. 5 - Prob. 5.136QACh. 5 - Prob. 5.137QACh. 5 - Prob. 5.138QACh. 5 - Prob. 5.139QACh. 5 - Prob. 5.140QA
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- Solid sulfur normally consists of crystals of S8 molecules, but when heated strongly, the solid vaporizes to give S2 molecules (among other molecular species). Describe the bonding in S2 in molecular orbital terms, assuming the orbitals are analogous to those of the preceding period. What would you expect to happen to the sulfur sulfur bond length if two electrons were added to give the S22 ion? What would you expect to happen to the bond length if, instead, two electrons were taken away to give S22+?arrow_forwardThere are two different molecules with the formula N2F2: Is either molecule polar? Explain.arrow_forwardThe sulfamate ion, H2NSO3, can be thought of as having been formed from the amide ion, NH2, and sulphur trioxide, SO3. (a) What are the electron-pair and molecular geometries or the amide ion and or SO3? What are the hybridizations of the N and S atoms, respectively? (b) Sketch a structure for the sulfamate ion, and estimate the bond angles. (c) What changes in hybridization do you expect for N and S in the course of the reaction NH2 + SO3 H2NSO3? (d) Is SO3 the donor of an electron pair or the acceptor of an electron pair in the reaction with amide ion? Does the electrostatic potential map shown below confirm your prediction?arrow_forward
- Aspirin, or acetylsalicylic acid, has the formula C9H8O4 and the skeleton structure (a) Complete the Lewis structure and give the number of bonds and bonds in aspirin. (b) What is the hybridization about the CO2H carbon atom (colored blue)? (c) What is the hybridization about the carbon atom in the benzene-like ring that is bonded to an oxygen atom (colored red)? Also, what is the hybridization of the oxygen atom bonded to this carbon atom?arrow_forwardThe compound sketched below is acetylsalicylic acid, commonly known as aspirin. (a) What are the approximate values of the angles marked A, B, C, and D? (b) What hybrid orbitals are used by carbon atoms 1, 2, and 3ss?arrow_forwardThe bond length in C2 is 131 pm. Compare this with the bond lengths in C2H2 (120 pm), C2H4 (134 pm), and C2H6 (153 pm). What bond order would you predict for C2 from its bond length? Does this agree with the molecular orbital configuration you would predict for C2?arrow_forward
- Explain in terms of bonding theory why all four hydrogen atoms of allene, H2CCCH2, cannot lie in the same plane.arrow_forwarda Nitrogen trifluoride, NF3, is a relatively unreactive, colorless gas. How would you describe the bonding in the NF3 molecule in terms of valence bond theory? Use hybrid orbitals. b Silicon tetrafluoride, SiF4, is a colorless gas formed when hydrofluoric acid attacks silica (SiO2) or glass. Describe the bonding in the SiF4 molecule, using valence bond theory.arrow_forwardConsider the polyatomic ion IO65-. How many pairs of electrons are around the central iodine atom? What is its hybridization? Describe the geometry of the ion.arrow_forward
- The structure of amphetamine, a stimulant, is shown below. (Replacing one H atom on the NH2, or amino, group with CH3 gives methamphetamine a particularly dangerous drug commonly known as speed.) (a) What are the hybrid orbitals used by the C atoms of the C6 ring. by the C atoms of the side chain, and by the N atom? (b) Give approximate values for the bond angles A, B, and C. (c) How many bonds and bonds are in the molerule? (d) Is the molecule polar or nonpolar? (e) Amphetamine reacts readily with a proton (H+) in aqueous solution. Where does this proton attach to the molecule? Explain how the electrostatic potential map predicts this site of protonation.arrow_forwardWhat are the bond angles predicted by the VSEPR model about the carbon atom in the formate ion, HCO2? Considering that the bonds to this atom are not identical, would you expect the experimental values to agree precisely with the VSEPR values? How might they differ?arrow_forwardCinnamaldehyde ocaus naturally in cinnamon oil. (a) What is the most polar bond in the molecule? (b) How many bonds and how many bonds are there? (c) Is cis-trans isomerism possible? If so, draw the isomers of the molecule. (d) Give the hybridization of the C atoms in the molecule. (e) What are the values of the bond angles 1, 2, and 3 ?arrow_forward
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