Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 5.1, Problem 1P
Interpretation Introduction
Interpretation: An explanation corresponding to the fact that cellulose is water insoluble by considering its three-dimensional structure is to be stated.
Concept introduction: Carbohydrates are polyhydroxy
Cellulose is an insoluble complex carbohydrate i.e. polysaccharide consisting of a large number of glucose units. It is a
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Chapter 5 Solutions
Organic Chemistry (6th Edition)
Ch. 5.1 - Prob. 1PCh. 5.2 - Prob. 2PCh. 5.3 - Draw the mirror image of each compound. Label each...Ch. 5.3 - Prob. 4PCh. 5.3 - A molecule is achiral if it has a plane of...Ch. 5.6 - Prob. 17PCh. 5.6 - Prob. 18PCh. 5.7 - Prob. 19PCh. 5.7 - Prob. 20PCh. 5.7 - Problem 5.18 Compounds E and F are two isomers of...
Ch. 5.8 - Prob. 22PCh. 5.8 - Prob. 23PCh. 5.8 - Prob. 24PCh. 5.9 - Prob. 25PCh. 5.9 - Prob. 26PCh. 5.9 - Prob. 27PCh. 5.10 - Which of the following cyclic molecules are meso...Ch. 5.10 - Prob. 29PCh. 5.11 - Prob. 30PCh. 5.12 - Problem 5.28 The amino acid has the physical...Ch. 5.12 - Prob. 32PCh. 5.12 - Prob. 33PCh. 5.12 - Prob. 34PCh. 5.12 - Prob. 35PCh. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Prob. 41PCh. 5 - Prob. 42PCh. 5 - 5.40 Determine if each compound is identical to or...Ch. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 52PCh. 5 - Prob. 56PCh. 5 - Prob. 61PCh. 5 - Prob. 67PCh. 5 - Prob. 68PCh. 5 - Prob. 69PCh. 5 -
5.67 Artemisinin and mefloquine are widely used...Ch. 5 - 5.68 Saquinavir (trade name Invirase) is a...Ch. 5 - Prob. 72P
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- Provide an explanation for the fact that α-D-mannose is more stable thanβ-D-mannose, whereas the opposite is true for glucose.arrow_forwardExplain why lactose and maltose differs from sucrose in its chemical activity with Fehling’s, Benedict’s and using Seliwanoff’s reagents?arrow_forwardIt is well known that humans are able to digest amylose, but not cellulose. What structural features might be responsible this observation?arrow_forward
- Another hexose gives the same aldaric acid on oxidation as does d-glucose. Which one?arrow_forwardWhat is the structure of Cellulose in Open Structure(Fischer) and in Closed Structure (Haworth)?arrow_forward1. Identify the anomeric carbons on sucrose and explain how they are different from lactose and cellulose. 2. On Wikipedia (image pictures below) sucrose is labeled β-D-Fructofuranosyl α-D-glucopyranoside. But the anomeric carbon has the oxygen pointing down and other stereocenters inverted from that of fructose. Did Wikipedia incorrectly name it? Or can you explain why this is the case using structures of sucrose, fructose and glucose…arrow_forward
- What is the main structural difference between a. amylose and cellulose? b. amylose and amylopectin? c. amylopectin and glycogen? d. cellulose and chitin?arrow_forwardDraw the Haworth structures for the following: - alpha-D-Gulopyranose - beta-D-Sorbofuranose - the two possivle isomers of alpha-D-altrose (furanose and pyranose forms)arrow_forwardCellulose is treated with methanol, which methylates the reducing end of polysaccharides. (a) How many methyl groups would be incorporated per cellulose chain? Explain. (b) Relative to cellulose, how many methyl groups would be incorporated in a molecule of amylopectin? (more, less or the same?) Explain. (c) Cellulose is treated with dimethyl sylfate, which adds a methyl group to all free hydroxyl groups. The cellulose is then hydrolyzed to release all of its monosacharides. Draw the structure of the resulting monosaccharidearrow_forward
- 1 Draw D- glucose in a Fischer Projection. 2 Draw alpha-D- glucose and in the Hayworth (ring ) structure. 3 Draw the hydrolysis of maltose- the disaccharide composed of alpha D glucose molecules. 4 What is the chemical difference between cellulose and amylose NOTE- please dont explain too much explain to the pointarrow_forwardStarch is a polymer of:* Please choose one correct answet only A. Glucose B. Fructose C. Cellulose D. Amylose E/ None of the given optionsarrow_forwardUsing the cyclic structure (Haworth Formula) of sucrose, encircle the acetal link and explain why it is a non reducing sugar. explain do not copy from google,,,pls type answer if u canarrow_forward
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