Concept explainers
(a)
Interpretation: The increasing stability of carbocation is to be interpreted.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:
Tertiary >Secondary >Primary
(b)
Interpretation: The increasing stability of carbocation is to be interpreted.
Concept introduction: Intermediates like carbocation can rearrange to give more stable carbocation. A primary carbocation carries a positive charge on the primary carbon atom whereas a secondary carbocation has a positive charge on the secondary carbon atom. Due to more hyperconjugation and inductive effect, the order of stability is:
Tertiary >Secondary >Primary
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Chapter 6 Solutions
ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
- Rank the carbocation compounds below from most stable to least stable.arrow_forwardRank the following carbocations in order of decreasing stability (from the most stable to the least stable): O A B C D Earrow_forwardGive IUPAC name for the following compounds: (Specify stereochemistry when shown in the diagram.) Ph Hi CH3CH2 1st compound: 2nd compound: H HO OH "H H CHCH₂CH₂CH3arrow_forward
- Rank the carbocations from most to least stable: O A B N сarrow_forwardLabel each pair of alkenes as constitutional isomers or stereoisomers. Select the single best answer for each part below. Part 1 of 3 H₂C=CHCH₂CH₂CH₂CH₂CH₂CH3 and H₂CH₂CHC=CHCH₂CH₂CH₂CH₂ O stereoisomers O constitutional isomers Part 2 of 3 H₂C H Part 3 of 3 O constitutional isomers O stereoisomers H₂C H CH₂CH3 H₂C H X CH₂CH₂CH₂CH₂ H O constitutional isomers O stereoisomers X CH₂ H X H₂C 5 CH₂CH₂CH₂CH₂ H 00 ← B 00 Ar !arrow_forwardWhen (R)-3-bromo-2,3-dimethylpentane is treated with NaOH, four different alkenes are formed. Draw all four products and rank them in order of stability.arrow_forward
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