Explanation In the crystalline state any given molecules has its maximum possible number of nearest neighbours and hence has maximum intermolecular attractions with the largest possible stabilisation. If however we warm such a system, the molecule acquire on an average, the amount of KT of kinetic energy. When the energy become very high, some molecule can migrate to the lattice forcing other molecules aside and having behind a vacancy. It thus produces an abnormal co-ordination number. It is known that even a single abnormal co-ordination number among a few hundreds of atom is sufficient to produce a long range disorder, which is quite frequent in the ionic liquid.

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Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson

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Chapter 6, Problem 6.17P

Interpretation Introduction

To determine:

The structural features which inhibits the ionic liquids to solidify.

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Chapter 6, Problem 6.16A

Chapter 6, Problem 6.18P

Chapter 6 Solutions

Chemistry

Ch. 6 - Prob. 6.1P Ch. 6 - APPLY 6.2 Which of the following sets of ions are...Ch. 6 - Prob. 6.3P Ch. 6 - Conceptual APPLY 6.4 Which of the following...Ch. 6 - Prob. 6.5P Ch. 6 - Prob. 6.6A Ch. 6 - Prob. 6.7P Ch. 6 - Conceptual APPLY 6.8 The figure on the right...Ch. 6 - Prob. 6.9P Ch. 6 - Conceptual APPLY 6.10 Which of the indicated three...

Ch. 6 - Prob. 6.11P Ch. 6 - Prob. 6.12A Ch. 6 - Prob. 6.13P Ch. 6 - APPLY 6.14 Calculate the energy of electrostatic...Ch. 6 - Prob. 6.15P Ch. 6 - Conceptual APPLY 6.16 One of the following...Ch. 6 - Prob. 6.17P Ch. 6 - PROBLEM 6.18 Compare the following two ionic...Ch. 6 - PROBLEM 6.19 An ionic liquid consisting of a bulky...Ch. 6 - Where on the periodic table would you find the...Ch. 6 - Which of the following spheres is likely to...Ch. 6 - Circle the approximate part or parts of the...Ch. 6 - Prob. 6.23CP Ch. 6 - This figure represents the successive ionization...Ch. 6 - In the following drawings, red spheres represent...Ch. 6 - Which of the following drawings is more likely to...Ch. 6 - Prob. 6.27CP Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Which of the following alkali metal halides has...Ch. 6 - Three binary compounds are represented on the...Ch. 6 - Given the following values for the formation of...Ch. 6 - What is the difference between a covalent bond and...Ch. 6 - Prob. 6.33SP Ch. 6 - What is the difference between a molecule and an...Ch. 6 - Prob. 6.35SP Ch. 6 - How many protons and electrons are in each of the...Ch. 6 - What is the identity of the element X in the...Ch. 6 - Prob. 6.38SP Ch. 6 - Prob. 6.39SP Ch. 6 - Prob. 6.40SP Ch. 6 - Prob. 6.41SP Ch. 6 - What doubly positive ion has the following...Ch. 6 - Prob. 6.43SP Ch. 6 - Prob. 6.44SP Ch. 6 - Which element in the transition-metal series Sc...Ch. 6 - Prob. 6.46SP Ch. 6 - Prob. 6.47SP Ch. 6 - Prob. 6.48SP Ch. 6 - Prob. 6.49SP Ch. 6 - Prob. 6.50SP Ch. 6 - Prob. 6.51SP Ch. 6 - Prob. 6.52SP Ch. 6 - Prob. 6.53SP Ch. 6 - Prob. 6.54SP Ch. 6 - Prob. 6.55SP Ch. 6 - Prob. 6.56SP Ch. 6 - Prob. 6.57SP Ch. 6 - Prob. 6.58SP Ch. 6 - Prob. 6.59SP Ch. 6 - What is the relationship between the electron...Ch. 6 - Prob. 6.61SP Ch. 6 - Prob. 6.62SP Ch. 6 - Prob. 6.63SP Ch. 6 - Prob. 6.64SP Ch. 6 - Prob. 6.65SP Ch. 6 - Prob. 6.66SP Ch. 6 - Prob. 6.67SP Ch. 6 - Prob. 6.68SP Ch. 6 - Prob. 6.69SP Ch. 6 - Prob. 6.70SP Ch. 6 - Prob. 6.71SP Ch. 6 - Prob. 6.72SP Ch. 6 - Prob. 6.73SP Ch. 6 - Prob. 6.74SP Ch. 6 - Prob. 6.75SP Ch. 6 - Find the lattice energy of LiBr(s) in Table 6.3,...Ch. 6 - Prob. 6.77SP Ch. 6 - Prob. 6.78SP Ch. 6 - Prob. 6.79SP Ch. 6 - Prob. 6.80SP Ch. 6 - Prob. 6.81SP Ch. 6 - Prob. 6.82SP Ch. 6 - Prob. 6.83SP Ch. 6 - Use the data and the result in Problem 6.78 to...Ch. 6 - Prob. 6.85SP Ch. 6 - Prob. 6.86CP Ch. 6 - Prob. 6.87CP Ch. 6 - Prob. 6.88CP Ch. 6 - Prob. 6.89CP Ch. 6 - Prob. 6.90CP Ch. 6 - Prob. 6.91CP Ch. 6 - Prob. 6.92CP Ch. 6 - Prob. 6.93CP Ch. 6 - Prob. 6.94CP Ch. 6 - Prob. 6.95CP Ch. 6 - Prob. 6.96CP Ch. 6 - Prob. 6.97CP Ch. 6 - Prob. 6.98CP Ch. 6 - Consider the electronic structure of the element...Ch. 6 - Prob. 6.100MP Ch. 6 - Prob. 6.101MP

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