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(a)
Interpretation:
The number and kind of stereoisomers formed when given molecule is treated in presence of
Concept Introduction:
Geometric isomers: Two atoms with the same side location of the double bond are called cis isomers and two atoms with opposite side locations of the double bond are called Trans isomers.
R and S nomenclature: it is used to assign the molecule using CIP (Cahn-Ingold-Prelog) rules.
The CIP rules are as follows:
Select the chiral carbon and assign the numbers according to the decreasing
If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.
(b)
Interpretation:
The number and kind of stereoisomers formed when given molecule is treated in presence of
Concept Introduction:
Geometric isomers: Two atoms with the same side location of the double bond are called cis isomers and two atoms with opposite side locations of the double bond are called Trans isomers.
R and S nomenclature: it is used to assign the molecule using CIP (Cahn-Ingold-Prelog) rules.
The CIP rules are as follows:
Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.
If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.
(c)
Interpretation:
The number and kind of stereoisomers formed when given molecule is treated in presence of
Concept Introduction:
Geometric isomers: Two atoms with the same side location of the double bond are called cis isomers and two atoms with opposite side locations of the double bond are called Trans isomers.
R and S nomenclature: it is used to assign the molecule using CIP (Cahn-Ingold-Prelog) rules.
The CIP rules are as follows:
Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.
If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.
(d)
Interpretation:
The number and kind of stereoisomers formed when given molecule is treated in presence of
Concept Introduction:
Geometric isomers: Two atoms with the same side location of the double bond are called cis isomers and two atoms with opposite side locations of the double bond are called Trans isomers.
R and S nomenclature: it is used to assign the molecule using CIP (Cahn-Ingold-Prelog) rules.
The CIP rules are as follows:
Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.
If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.
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Chapter 6 Solutions
Organic Chemistry
- please provide reactants, and show stereochemistry where appropriatearrow_forwardProvide the major products (write “no reaction” if you think so) for the following reactions with correct stereochemistry.arrow_forwardPredict the products of the following reactions. Show stereochemistry when applicable.arrow_forward
- Predict the product of the following reactions. Show stereochemistry when applicable.arrow_forwardPredict the products of the following reactions, showing stereochemistry where appropriate.arrow_forwardGive the major organic product(s) or reagents needed for the following reactions or sequences of reactions. Show all relevant stereochemistry.arrow_forward
- Predict the organic products of the reaction. Show stereochemistry clearly.arrow_forwardProvide either the missing product or missing reagent for the following reactions. Provide stereochemistry where relevant and if no reaction occurs, say soarrow_forwardPredict the products and indicate the relative stereochemistry for the following transformations. When necessary indicate the major productarrow_forward
- Give the major organic products from the following reactionsarrow_forwardPredict the MAJOR carbon-containing product(s) of the following reactions. Show stereochemistry where applicable and draw out ALL stereoisomers that are formed as MAJOR products. Assume all reagents are in excess.arrow_forwardComplete the following reactions by providing the correct product(s), starting materials, or reagents. When appropriate, products should have the correct stereochemistryarrow_forward
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