To draw: The alpha and beta anomers of D-mannose. Introduction: Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Question

Want to see the full answer?

Answer 1

Question

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 2

Question

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Answer 6

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Answer 7

Chapter 6, Problem 6.61AP

Summary Introduction

To draw:

The alpha and beta anomers of D-mannose.

Introduction:

Diastereomers are those stereoisomers who differ in orientation of two chiral centers due to which the isomers are not the mirror images of each other. The cyclic forms of diastereoisomeric sugars which differ at the anomeric carbon (carbonyl carbon which reacts to form hemiacetal) are known as anomers. Hemiacetal is formed when the carbonyl carbon (partially positive) and oxygen of hydroxyl group (partially negative) forms a bond. The hemiacetal anomers exist in alpha and beta forms based on the site of substituent at anomeric carbon.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 6 - Prob. 6.1PP Ch. 6 - Prob. 6.2PP Ch. 6 - Prob. 6.3PP Ch. 6 - Prob. 6.4PP Ch. 6 - Prob. 6.5PP Ch. 6 - Classify each of the following alcohols as a...Ch. 6 - Prob. 6.7PP Ch. 6 - Prob. 6.8PP Ch. 6 - Prob. 6.9PP Ch. 6 - Prob. 6.10PP

Solution Summary: The author describes the alpha and beta anomers of D-mannose.

Concept explainers

Want to see the full answer?

Chapter 6 Solutions