Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 6, Problem 6.68QP
Most organic acids can be represented as RCOOH, where COOH is the carboxyl group and R is the rest of the molecule. [For example, R is CH3 in acetic acid (CH3COOH).] (a) Draw a Lewis structure for the carboxyl group, (b) Upon ionization, the carboxyl group is converted to the carboxylate group (COO−). Draw resonance structures for the carboxylate group.
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(a) Describe the molecule xenon trioxide, XeO3, using four possible Lewis structures, one each with zero, one, two, or three Xe—O double bonds. (b) Do any of these resonance structures satisfy the octet rule for every atom in the molecule? (c) Do any of the four Lewis structures have multiple resonance structures? If so, how many resonance structures do you find? (d) Which of the Lewis structures in (a) yields the most favorable formal charges for the molecule?
The C¬O bond length in carbon monoxide, CO, is 1.13 Å, whereas the C¬Obond length in CO2 is 1.24 Å. Without drawing a Lewis structure, do you think thatCO contains a single, double, or triple bond?
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Chapter 6 Solutions
Chemistry: Atoms First
Ch. 6.2 - Classify the following bonds as nonpolar, polar,...Ch. 6.2 - Classify the following bonds as nonpolar, polar,...Ch. 6.2 - Prob. 1PPBCh. 6.2 - Electrostatic potential maps are shown for HCl and...Ch. 6.2 - Prob. 6.2WECh. 6.2 - Prob. 2PPACh. 6.2 - Prob. 2PPBCh. 6.2 - Prob. 2PPCCh. 6.2 - Prob. 6.3WECh. 6.2 - Prob. 3PPA
Ch. 6.2 - Prob. 3PPBCh. 6.2 - Prob. 6.2.1SRCh. 6.2 - Prob. 6.2.2SRCh. 6.2 - Using data from Table 6.2, calculate the magnitude...Ch. 6.2 - Prob. 6.2.4SRCh. 6.3 - Draw the Lewis structure for carbon disulfide...Ch. 6.3 - Prob. 4PPACh. 6.3 - Prob. 4PPBCh. 6.3 - Prob. 4PPCCh. 6.3 - Prob. 6.3.1SRCh. 6.3 - Prob. 6.3.2SRCh. 6.4 - The widespread use of fertilizers has resulted in...Ch. 6.4 - Prob. 5PPACh. 6.4 - Prob. 5PPBCh. 6.4 - Prob. 5PPCCh. 6.4 - Formaldehyde (CH2O), which can be used 10 preserve...Ch. 6.4 - Prob. 6PPACh. 6.4 - Prob. 6PPBCh. 6.4 - Prob. 6PPCCh. 6.4 - Prob. 6.4.1SRCh. 6.4 - Prob. 6.4.2SRCh. 6.5 - Prob. 6.7WECh. 6.5 - Prob. 7PPACh. 6.5 - Prob. 7PPBCh. 6.5 - Prob. 7PPCCh. 6.5 - How many resonance structures can be drawn for the...Ch. 6.5 - Indicate which of the following are resonance...Ch. 6.6 - Prob. 6.8WECh. 6.6 - Prob. 8PPACh. 6.6 - Prob. 8PPBCh. 6.6 - Prob. 8PPCCh. 6.6 - Prob. 6.9WECh. 6.6 - Prob. 9PPACh. 6.6 - Prob. 9PPBCh. 6.6 - Elements in the same group exhibit similar...Ch. 6.6 - Draw three resonance structures for the hydrogen...Ch. 6.6 - Draw two resonance structures for each speciesone...Ch. 6.6 - Prob. 10PPCCh. 6.6 - Prob. 6.6.1SRCh. 6.6 - Which elements cannot have more than an octet of...Ch. 6.6 - How many electrons are around the central atom in...Ch. 6 - Which of the following atoms must always obey the...Ch. 6 - Prob. 6.2KSPCh. 6 - Prob. 6.3KSPCh. 6 - How many lone pairs are on the central atom in the...Ch. 6 - Prob. 6.1QPCh. 6 - Prob. 6.2QPCh. 6 - Prob. 6.3QPCh. 6 - Prob. 6.4QPCh. 6 - Prob. 6.5QPCh. 6 - Prob. 6.6QPCh. 6 - Prob. 6.7QPCh. 6 - Prob. 6.8QPCh. 6 - For each of the following pairs of elements, state...Ch. 6 - Define electronegativity and explain the...Ch. 6 - Prob. 6.11QPCh. 6 - Prob. 6.12QPCh. 6 - Prob. 6.13QPCh. 6 - Prob. 6.14QPCh. 6 - Prob. 6.15QPCh. 6 - Prob. 6.16QPCh. 6 - Arrange the following bonds in order of increasing...Ch. 6 - Prob. 6.18QPCh. 6 - Prob. 6.19QPCh. 6 - Prob. 6.20QPCh. 6 - Prob. 6.21QPCh. 6 - Prob. 6.22QPCh. 6 - Prob. 6.23QPCh. 6 - Prob. 6.24QPCh. 6 - Prob. 6.25QPCh. 6 - Prob. 6.26QPCh. 6 - Prob. 6.27QPCh. 6 - Prob. 6.28QPCh. 6 - Prob. 6.30QPCh. 6 - Prob. 6.31QPCh. 6 - Prob. 6.32QPCh. 6 - Prob. 6.33QPCh. 6 - Prob. 6.34QPCh. 6 - Draw all of the resonance structures for the...Ch. 6 - Prob. 6.36QPCh. 6 - Prob. 6.37QPCh. 6 - Draw three resonance structures for the molecule...Ch. 6 - Draw three reasonable resonance structures for the...Ch. 6 - Indicate which of the following are resonance...Ch. 6 - Prob. 6.41QPCh. 6 - Prob. 6.42QPCh. 6 - Draw a resonance structure of the guanine molecule...Ch. 6 - Prob. 6.44QPCh. 6 - Give three examples of compounds that do not...Ch. 6 - Prob. 6.46QPCh. 6 - Prob. 6.47QPCh. 6 - Prob. 6.48QPCh. 6 - Prob. 6.49QPCh. 6 - Prob. 6.50QPCh. 6 - Prob. 6.51QPCh. 6 - Prob. 6.52QPCh. 6 - Prob. 6.53QPCh. 6 - Draw Lewis structures for the radical species ClF2...Ch. 6 - Prob. 6.55QPCh. 6 - Prob. 6.56QPCh. 6 - Prob. 6.57QPCh. 6 - Prob. 6.58QPCh. 6 - Prob. 6.59QPCh. 6 - Prob. 6.60QPCh. 6 - Give an example of an ion or molecule containing...Ch. 6 - Prob. 6.62QPCh. 6 - Prob. 6.63QPCh. 6 - Prob. 6.64QPCh. 6 - Are the following statements true or false? (a)...Ch. 6 - Prob. 6.66QPCh. 6 - Prob. 6.67QPCh. 6 - Most organic acids can be represented as RCOOH,...Ch. 6 - Prob. 6.69QPCh. 6 - Prob. 6.70QPCh. 6 - Prob. 6.71QPCh. 6 - The following species have been detected in...Ch. 6 - Prob. 6.73QPCh. 6 - Prob. 6.74QPCh. 6 - The triiodide ion (I3) in which the I atoms are...Ch. 6 - Prob. 6.76QPCh. 6 - Prob. 6.77QPCh. 6 - The chlorine nitrate (ClONO2) molecule is believed...Ch. 6 - Prob. 6.79QPCh. 6 - For each of the following organic molecules draw a...Ch. 6 - Prob. 6.81QPCh. 6 - Draw Lewis structures for the following organic...Ch. 6 - Draw Lewis structures for the following four...Ch. 6 - Prob. 6.84QPCh. 6 - Prob. 6.85QPCh. 6 - Draw three resonance structures for (a) the...Ch. 6 - Prob. 6.87QPCh. 6 - Prob. 6.88QPCh. 6 - Prob. 6.89QPCh. 6 - Draw a Lewis structure for nitrogen pentoxide...Ch. 6 - Prob. 6.91QPCh. 6 - Nitrogen dioxide (NO2) is a stable compound....Ch. 6 - Prob. 6.93QPCh. 6 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 6 - Prob. 6.95QPCh. 6 - Prob. 6.96QPCh. 6 - In 1999 an unusual cation containing only nitrogen...Ch. 6 - Prob. 6.98QPCh. 6 - Prob. 6.99QPCh. 6 - Electrostatic potential maps for three compounds...
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