Custom eBook for Organic Chemistry
2nd Edition
ISBN: 9798214171104
Author: Straumanis
Publisher: Cengage Custom
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Textbook Question
Chapter 7, Problem 10E
True or False: If you perform a chair flip on cis-1,4-dichlorocyclohexane, the result is still called
cis-1,4-dichlorocyclohexane.
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2-methylbutane
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Here is the chemical structure of 2-bromobutane:
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Decide whether each molecule in the table below is another molecule of 2-bromobutane, a molecule of an isomer of 2-bromobutane, or a molecule of an entirely
different compound.
molecule
relationship to 2-bromobutane
CH,
(Choose one)
H,c=ċ=CH,-Br
Explanation
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Chapter 7 Solutions
Custom eBook for Organic Chemistry
Ch. 7 - Prob. 1CTQCh. 7 - Prob. 2CTQCh. 7 - Prob. 3CTQCh. 7 - Draw wedge and dash skeletal representations of...Ch. 7 - Label each ring in Figure 7.2 cis or trans.Ch. 7 - Prob. 6CTQCh. 7 - Prob. 7CTQCh. 7 - Prob. 8CTQCh. 7 - a model of cyclohexane in a chair conformation,...Ch. 7 - Prob. 10CTQ
Ch. 7 - Prob. 11CTQCh. 7 - Fill in the blanks: cis-1,3-Dimethylcyclohexane...Ch. 7 - Prob. 13CTQCh. 7 - Prob. 14CTQCh. 7 - Prob. 15CTQCh. 7 - Prob. 16CTQCh. 7 - Prob. 17CTQCh. 7 - Prob. 18CTQCh. 7 - Draw chair representations of...Ch. 7 - Which stereoisomer in the previous question is...Ch. 7 - Prob. 21CTQCh. 7 - Prob. 1ECh. 7 - Label each of the following as cis, trans or...Ch. 7 - Which pair has more in common with one another?Ch. 7 - Prob. 4ECh. 7 - Prob. 5ECh. 7 - Prob. 6ECh. 7 - Fill in the table by drawing a representation of a...Ch. 7 - Prob. 9ECh. 7 - True or False: If you perform a chair flip on...Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Draw trans-1-tert-butyl-3-methylcyclohexane in its...Ch. 7 - Build a model of methylcyclohexane, and use the...
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- Modify the structure of cyclohexane to show 1,1-dimethylcyclohexane. H₂C 1 H₂C CH₂ CH₂ Modify the structure of cyclohexane to show 1,3-dimethylcyclohexane. H₂C | H₂C UI CH₂ 1 CH₂arrow_forwardThe molecule below would be named O: = H-C HHH ||| O-C-C-C-H | | | HHH A) methyl propanoate B) methyl propyl ester C) propyl methanoate D) methylpropyl etherarrow_forwardWrite the systematic name of each organic molecule: O || CH3–CH2–CH2–CH2−C−N–CH2–CH2–CH3 H₂N CH3 CH₂- structure || || CH₂ CH₂ CH3 C-CH₂-CH3 NH C−NH–CH,—CH,—CH3 name 1 0arrow_forward
- Write the systematic name of each organic molecule: CH3 structure -C−NH–CH2−CH2CH3 || H₂N-C-CH₂ -CH2–CH2–CH2–CH3 CH3 CH2–CH2–NH–C–CH2–CH3 name 11 0 0arrow_forward16. Choose the correct New- man projection that cor- responds to point A on the graph of chemical potential energy vs. tation about the C2-C3 ro- bond of butane. A) H H CH3 H CH3 B) H 个 Potential Energy H H CH3 d CH3 H H 0 A 60 C) HH 120 180 240 300 Degrees rotation →→→→ H CH3 CH3 H 360 H3C CH3 пон D) H A H Harrow_forwardUsing the following bond energies, calculate the molar heat of hydrogenation, AHhydrogenation CH=CH(g) + 2H₂(g) →→→ CH₂CH₂(g) Bond Bond Strength (kJ/mol) C-C 348 839 411 432 || C=C C-H H-H kJ/molarrow_forward
- Tertiary alcohol has its hydroxyl group attached to the carbon atom that is connected to 4 alkyl groups. True or Falsearrow_forwardCommon System: 1. C4H9NHC₂H5 (sec.) 0 || 2. CH3(CH₂)2C(CH3)2COC(CH3)3 3. C₂H5CON(C₂H5)2arrow_forwardConsider 2-methylbutane (isopentane). Sighting along the C2-C3 bond, Draw a Newman projection formula for the most stable conformation. Based on your drawing, determine the total strain energy for this conformation. Given the following strain energies with respect to atoms/groups bonded to C-C (one atom/group bonded to each C) H H eclipsed: 4 kJ/mol CH3 H eclipsed: 6 kJ/mol CH3 CH3 eclipsed: 11 kJ/mol CH3 CH3 gauche staggered: 3.8 kJ/mol Select one: O A. 11 kJ/mol O B. 7.6 kJ/mol O C. 3.8 kJ/mol O D. 14.8 kJ/molarrow_forward
- One of the first drugs to be approved for use in treatment of acquired immune deficiency syndrome (AIDS) was azidothymidine (AZT). CH3 C6 || Cs- H. N5 C8- H H. H-O- H C4 H C2-C3 H N1 N3arrow_forwarda) Draw all Newman projections of your molecule's conformations in which the CH3 group and the H of the CHY2 group are positioned 'ANTI' to each other. Be sure to put in the correct X and Y atoms, bonded to the correct C atoms, for your molecule. X = FY=I Conformations = 60 deg and - 180 deg 60 deg dihedral angle = - 179.987 deg 180 deg · - dihedral angle = 179.814 degarrow_forwardConsider the isomers of tert-butylcyclohexanol in conformational structures. Two are cis-2-tert-butylcyclohexanol and two are cis-3-tert-butylcyclohexanol. Indicate which is the more stable conformation for each pair, and indicate which of all four conformations is the most stable. FIX a box OH HO OH A Select the more stable conformation of cis-2-tert-butylcyclohexanol. B OD C B C D ☐A C OH Select the more stable conformation of cis-3-tert-butylcyclohexanol.arrow_forward
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