Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 7, Problem 7.13NP
Interpretation Introduction

Interpretation : It should be shown that in the limit of low density, the van der Waals and Redlich-Kwong equations of state can be reduced to the ideal gas equation of state.

Concept Introduction :

Van der Waals equation of state:

  P=RTVmbaVm2=nRTVnbn2aV2

P − pressure

R − universal gas constant

Vm − molar volume

n − number of moles

a − correction for volume

b − correction for attractive force

Redlich-Kwong equation of state:

  P=RTVmbaT1Vm(Vm+b)=nRTVnbn2aT1V(V+nb)

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