Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 7, Problem 7.15NP
Interpretation Introduction

Interpretation : Expressions for β=1/V(V/T)P and κ=1/V(V/T)T should be derived from the Berthelot equation in terms of V, T and P.

Concept Introduction :

The Berthelot equation is represented as follows:

  Vm=(RTP)+b(aRT2)

Here,

Vm − molar volume

R − universal constant

T −temperature

P − pressure

a and b − parameters that are determined empirically

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