Concept explainers
(a)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
On moving right to left across a row in periodic table, nucleophilicity as well as the basicity increases. Therefore, the order of increasing nucleophilicity is
The order of increasing nucleophilicity is
(b)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good nucleophiles are strong base whose conjugate acids have high
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
The size of
The order of increasing nucleophilicity is
(c)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good nucleophiles are strong base whose conjugate acids have high
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
A solvent in which hydrogen atom is bonded to electronegative
The order of increasing nucleophilicity is
(d)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good nucleophiles are strong base whose conjugate acids have high
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
The nucleophilicity and basicity are directly related to each other in
On moving down the group in a periodic table and left to right in a period, basicity decreases and hence, nucleophilicity decreases. Sulfur lies below oxygen atom and nitrogen lies left to oxygen atom in a periodic table. Thus, the order of increasing nucleophilicity is
The order of increasing nucleophilicity is
(e)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good nucleophiles are strong base whose conjugate acids have high
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
The nucleophilicity and basicity are directly related to each other in polar aprotic solvent. Acetone is a polar aprotic solvent.
On moving down the group in a periodic table and left to right in a period, basicity decreases and hence, nucleophilicity decreases. Chlorine lies below fluorine atom and nitrogen lies left to fluorine in a periodic table. Thus, the order of increasing nucleophilicity is
The order of increasing nucleophilicity is
(f)
Interpretation: The given species are to be arranged in order of increasing nucleophilicity.
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom. The good nucleophiles are strong base whose conjugate acids have high
Answer to Problem 7.54P
The order of increasing nucleophilicity is
Explanation of Solution
A solvent in which hydrogen atom is bonded to electronegative
The order of increasing nucleophilicity is
Want to see more full solutions like this?
Chapter 7 Solutions
Organic Chemistry-Package(Custom)
- give the major products of each reactionarrow_forwardDraw the products of each reaction. Assume excess halogen is present.arrow_forwardDraw the product of nucleophilic substitution with each neutral nucleophile. When the initial substitution product can lose a proton to form a neutral product, draw the product after proton transfer.arrow_forward
- Step 3 reagent list hcl chromic acid, h2so4 socl2 co2 then water pcc, dcmarrow_forwardDraw the product of each reaction.arrow_forward1. What type of mechanism step is shown below? OH₂ + H₂O a. Nucleophilic addition c. Electrophile elimination b. Electrophilic addition d. Nucleophile elimination 2. What type of mechanism step is shown below? a. Nucleophilic addition c. Electrophile elimination b. Electrophilic addition d. Nucleophile elimination 3. What type of mechanism step is shown below? H-CI CI a. Nucleophilic addition c. Electrophile elimination b. Electrophilic addition d. Nucleophile elimination 4. What type of mechanism step is shown below? I a. Nucleophilic addition c. Electrophile elimination b. Electrophilic addition d. Nucleophile eliminationarrow_forward
- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CNarrow_forwardDraw the organic product(s) formed when CH3CH2CH2OH is treated with each reagent. a.H2SO4 b.NaH c.HCl + ZnCl2 d.HBr e.SOCl2, pyridine f.PBr3 g.TsCl, pyridine h. [1] NaH; [2] CH3CH2Br [1] i.TsCl, pyridine; [2] NaSH j.POCl3, pyridinearrow_forwardH30+ /A а. H3C-OH H3O+ /A b. CH,CH-OH РОСiз / рyridine C. HO. OH H2SO4 /A d.arrow_forward