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Rank the species in each group in order of increasing leaving group ability.
a.
b.
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Chapter 7 Solutions
Organic Chemistry-Package(Custom)
- Choose the correct product for the given reaction. HBr Br В. А. Br Br С. D. Br Br O A Вarrow_forward4. Predict the product of the nitration reactions CH3 HNO3 H2SO4 CI of HO, CHO N. LOCH2CH2CH3 Br2 NH2 5. A. Which of the following is the most acidic? least acidic? HO. HO, THO. OCH3 NO2 В. С. А. B. Rank the following compounds in order of increasing acidity, putting the least acidic first. CI CI CI HO, HO. HO. HO. CI CI CI %3D II IVarrow_forwardWhich is the more stable base? a. Br− or I− b. CH3O− or CH3S− c. CH3CH2O− or CH3COO− d. H2C CH or HC C− e. FCH2CH2COO− or CH2CH2COO- f. CLCH2CH2O- or CL2CHCH2O-arrow_forward
- Question 4: In the following E2 reaction, which hydrogen will preferentially be removed? Hd Hc Hb Hb Hf He I Ha A. Ha B. Hb C. Hc D. Hd E. He Hb potassium tertbutoxide tertbutanolarrow_forwardWhat does a value of K eq greater than 1 mean?A. More reactants than products exist at equilibrium.B. More products than reactants exist at equilibrium.C. The rate of the forward reaction is high atequilibrium.D. The rate of the reverse reaction is high atequilibrium.arrow_forward6. Circle the most acidic hydrogen in each compound. NH, HS HO. H,C CH What is the order of acid strength from strongest acid to weakest acid? CH,COH CF,CH,COH CFCOH CC,COH II II IV Rank the following species in order of increasing acidity. Explain your reasons as you do: CH3OH 7. a) HF NH3 H2SO4 CH3COOH H30+ H20 Rank the following species in order of increasing basicity. Explain your reasons as you do: H2O 8. b) NH3 CH30- CH3COO NAOH NH2- HSO4-arrow_forward
- What is the CORRECT product A for the following reaction? i. Mg, Et,O ii. CO2 iii. H;O* i. LİAH, Et,O ii. H2O Br Aarrow_forward9. What product is expected to be produced? EtoⓇ ii oft 2. Ph Br 1. Eto Na, EtOH OEt 3. NaOH H3O+ 4. heat, -CO2 u u OEt A. Ph B. Ph OH C. Ph D. All of them.arrow_forwardThe following enamine is in equilibrium with which compounds when in trace acidic conditions? a. 2-butene, N(CH3)2H b. 2-butanone, N(CH3)2H c. butanal, N(CH3)2H d. 2-butene-1-ol, LIAIH e. butanoic acid, N(CH3)2H N(CH3)2arrow_forward
- Discuss the different experimental conditions used to give the major and minor product distributions shown. 1. LDA 2. OH ОН H. 3. acid major minor 1. LDA 2. Он О OH TH. 3. acid minor majorarrow_forward1. Rank each set of three alcohols in terms of increasing acidity, "1" being least acidic, and "3" being most acidic. goos CCI3 CI3C. Cl3 а. ОН ОН OH b. OH ОН ОН OH С. HOarrow_forward19. From each pair, circle the stronger base. or or or or or CH,NH or CH,CH2arrow_forward
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