Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Question
Chapter 7, Problem 7B.1BST
Interpretation Introduction
Interpretation:
The remaining concentration of
Concept Introduction:
According to the integrated rate law for the first order reaction, the concentration of reactant is the exponential function of time. The two equations that represent the integrated rate law for the first order kinetics is shown below.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionChapter 7 Solutions
Chemical Principles: The Quest for Insight
Ch. 7 - Prob. 7A.1ASTCh. 7 - Prob. 7A.1BSTCh. 7 - Prob. 7A.2ASTCh. 7 - Prob. 7A.2BSTCh. 7 - Prob. 7A.3ASTCh. 7 - Prob. 7A.3BSTCh. 7 - Prob. 7A.4ASTCh. 7 - Prob. 7A.4BSTCh. 7 - Prob. 7A.1ECh. 7 - Prob. 7A.2E
Ch. 7 - Prob. 7A.3ECh. 7 - Prob. 7A.4ECh. 7 - Prob. 7A.7ECh. 7 - Prob. 7A.8ECh. 7 - Prob. 7A.9ECh. 7 - Prob. 7A.10ECh. 7 - Prob. 7A.11ECh. 7 - Prob. 7A.12ECh. 7 - Prob. 7A.13ECh. 7 - Prob. 7A.14ECh. 7 - Prob. 7A.15ECh. 7 - Prob. 7A.16ECh. 7 - Prob. 7A.17ECh. 7 - Prob. 7A.18ECh. 7 - Prob. 7B.1ASTCh. 7 - Prob. 7B.1BSTCh. 7 - Prob. 7B.2ASTCh. 7 - Prob. 7B.2BSTCh. 7 - Prob. 7B.3ASTCh. 7 - Prob. 7B.3BSTCh. 7 - Prob. 7B.4ASTCh. 7 - Prob. 7B.4BSTCh. 7 - Prob. 7B.5ASTCh. 7 - Prob. 7B.5BSTCh. 7 - Prob. 7B.1ECh. 7 - Prob. 7B.2ECh. 7 - Prob. 7B.3ECh. 7 - Prob. 7B.4ECh. 7 - Prob. 7B.5ECh. 7 - Prob. 7B.6ECh. 7 - Prob. 7B.7ECh. 7 - Prob. 7B.8ECh. 7 - Prob. 7B.9ECh. 7 - Prob. 7B.10ECh. 7 - Prob. 7B.13ECh. 7 - Prob. 7B.14ECh. 7 - Prob. 7B.15ECh. 7 - Prob. 7B.16ECh. 7 - Prob. 7B.17ECh. 7 - Prob. 7B.18ECh. 7 - Prob. 7B.19ECh. 7 - Prob. 7B.20ECh. 7 - Prob. 7B.21ECh. 7 - Prob. 7B.22ECh. 7 - Prob. 7C.1ASTCh. 7 - Prob. 7C.1BSTCh. 7 - Prob. 7C.2ASTCh. 7 - Prob. 7C.2BSTCh. 7 - Prob. 7C.1ECh. 7 - Prob. 7C.2ECh. 7 - Prob. 7C.3ECh. 7 - Prob. 7C.4ECh. 7 - Prob. 7C.5ECh. 7 - Prob. 7C.6ECh. 7 - Prob. 7C.7ECh. 7 - Prob. 7C.8ECh. 7 - Prob. 7C.9ECh. 7 - Prob. 7C.11ECh. 7 - Prob. 7C.12ECh. 7 - Prob. 7D.1ASTCh. 7 - Prob. 7D.1BSTCh. 7 - Prob. 7D.2ASTCh. 7 - Prob. 7D.2BSTCh. 7 - Prob. 7D.1ECh. 7 - Prob. 7D.2ECh. 7 - Prob. 7D.3ECh. 7 - Prob. 7D.5ECh. 7 - Prob. 7D.6ECh. 7 - Prob. 7D.7ECh. 7 - Prob. 7D.8ECh. 7 - Prob. 7E.1ASTCh. 7 - Prob. 7E.1BSTCh. 7 - Prob. 7E.1ECh. 7 - Prob. 7E.2ECh. 7 - Prob. 7E.3ECh. 7 - Prob. 7E.4ECh. 7 - Prob. 7E.5ECh. 7 - Prob. 7E.6ECh. 7 - Prob. 7E.7ECh. 7 - Prob. 7E.8ECh. 7 - Prob. 7E.9ECh. 7 - Prob. 1OCECh. 7 - Prob. 7.1ECh. 7 - Prob. 7.2ECh. 7 - Prob. 7.3ECh. 7 - Prob. 7.4ECh. 7 - Prob. 7.5ECh. 7 - Prob. 7.6ECh. 7 - Prob. 7.7ECh. 7 - Prob. 7.9ECh. 7 - Prob. 7.11ECh. 7 - Prob. 7.14ECh. 7 - Prob. 7.15ECh. 7 - Prob. 7.17ECh. 7 - Prob. 7.19ECh. 7 - Prob. 7.20ECh. 7 - Prob. 7.23ECh. 7 - Prob. 7.25ECh. 7 - Prob. 7.26ECh. 7 - Prob. 7.29ECh. 7 - Prob. 7.30ECh. 7 - Prob. 7.31E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Nitryl fluoride is an explosive compound that can be made by oxidizing nitrogen dioxide with fluorine: 2 NO2(g) + F2(g) → 2 NO2F(g) Several kinetics experiments, all done at the same temperature and involving formation of nitryl fluoride, are summarized in this table: Write the rate law for the reaction. Determine what the order of the reaction is with respect to each reactant and each product. Calculate the rate constant k and express it in appropriate units.arrow_forwardChlorine dioxide, ClO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives ClO3 and ClO2 ions. 2ClO2(aq)+2OH(aq)ClO3(aq)+ClO2(aq)+H2O To obtain the rate law for this reaction, the following experiments were run and, for each, the initial rate of reaction of ClO2 was determined. Obtain the rate law and the value of the rate constant.arrow_forwardIsomerization of CH3NC occurs slowly when CH3NC is heated. CH3NC(g) CH3CN(g) To study the rate of this reaction at 488 K, data on [CH3NC] were collected at various times. Analysis led to the following graph. (a) What is the rate law for this reaction? (b) What is the equation for the straight line in this graph? (c) Calculate the rate constant for this reaction. (d) How long does it take for half of the sample to isomerize? (e) What is the concentration of CH3NC after 1.0 104 s?arrow_forward
- Nitrosyl bromide, NOBr, is formed from NO and Br2: 2 NO(g) + Br2(g) 2 NOBr(g) Experiments show that this reaction is second-order in NO and first-order in Br2. (a) Write the rate equation for the reaction. (b) How does the initial reaction rate change if the concentration of Br2 is changed from 0.0022 mol/L to 0.0066 mol/L? (c) What is the change in the initial rate if the concentration of NO is changed from 0.0024 mol/L to 0.0012 mol/L?arrow_forwardThe decomposition of ozone is a second-order reaction with a rate constant of 30.6 atm1 s1 at 95 C. 2O3(g)3O2(g) If ozone is originally present at a partial pressure of 21 torr, calculate the length of time needed for the ozone pressure to decrease to 1.0 torr.arrow_forwardCyclopropane, C3H6, is converted to its isomer propylene, CH2CHCH3, when heated. The rate law is first order in cyclopropane, and the rate constant is 6.0 104/s at 500C. If the initial concentration of cyclopropane is 0.0226 mol/L, what is the concentration after 525 s?arrow_forward
- The Raschig reaction produces the industrially important reducing agent hydrazine, N2H4, from ammonia, NH3, and hypochlorite ion, OCl−, in basic aqueous solution. A proposed mechanism is Step 1: Step 2: Step 3: What is the overall stoichiometric equation? Which step is rate-limiting? What reaction intermediates are involved? What rate law is predicted by this mechanism?arrow_forwardAt 500 K in the presence of a copper surface, ethanol decomposes according to the equation C2H5OH(g)CH3CHO(g)+H2(g) The pressure of C2H5OH was measured as a function of time and the following data were obtained: Time(s) PC2H5OH(torr) 0 250. 100. 237 200. 224 300. 211 400. 198 500. 185 Since the pressure of a gas is directly proportional to the concentration of gas, we can express the rate law for a gaseous reaction in terms of partial pressures. Using the above data, deduce the rate law, the integrated rate law, and the value of the rate constant, all in terms of pressure units in atm and time in seconds. Predict the pressure of C2H5OH after 900. s from the start of the reaction. (Hint: To determine the order of the reaction with respect to C2H5OH, compare how the pressure of C2H5OH decreases with each time listing.)arrow_forwardOzone, O3, in the Earths upper atmosphere decomposes according to the equation 2 O3(g) 3 O2(g) The mechanism of the reaction is thought to proceed through an initial fast, reversible step followed by a slow, second step. Step 1: Fast, reversible O3(g) O2(g) + O(g) Step 2: Slow O3(g) + O(g) 2 O2(g) (a) Which of the steps is rate-determining? (b) Write the rate equation for the rate-determining steparrow_forward
- The decomposition of iodoethane in the gas phase proceeds according to the following equation: C2H5I(g)C2H4(g)+HI(g) At 660. K, k = 7.2 104 sl; at 720. K, k = 1.7 102 sl. What is the value of the rate constant for this first-order decomposition at 325C? If the initial pressure of iodoethane is 894 torr at 245C, what is the pressure of iodoethane after three half-lives?arrow_forwardHydrogen iodide decomposes when heated, forming H2(g) and I2(g). The rate law for this reaction is [HI]/t = k[HI]2. At 443C, k = 30. L/mol min. If the initial HI(g) concentration is 1.5 102 mol/L, what concentration of HI(g) will remain after 10. minutes?arrow_forwardThe thermal decomposition of nitryl chloride, NO2Cl, 2NO2Cl(g)2NO2(g)+Cl2(g) is thought to occur by the mechanism shown in the following equations: NO2Clk1NO2+Cl(slowstep)NO2Cl+Clk2NO2+Cl2(faststep) What rate law is predicted by this mechanism?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781285199023Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Kinetics: Chemistry's Demolition Derby - Crash Course Chemistry #32; Author: Crash Course;https://www.youtube.com/watch?v=7qOFtL3VEBc;License: Standard YouTube License, CC-BY