Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 7.4, Problem 7.2P
Problem 7-2
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2NO(g)+O2(g)⇌2NO2(g) + Heat
a) where will the reaction be shifted (right or left) if there is an increase in temperature?
b) increase in pressure
c) increase in volume
d.) addition of catalyst
e.) cooling the system
f.) What happens to the concentration of NO2 if there is a decrease in pressure?
g.) removal of NO2
h.) adding more O2
i.) removal of NO?
Answer plz fast
The balanced equation for this reaction is shown below: 3 NaHCO3(aq) + H3C3H5O7(aq) → Na3C3H5O7(aq) + 3 CO2(g) + 3 H20(l) Devise an experiment to determine the overall order of reaction (be specific in your answer)...
Answer plz !
The balanced equation for this reaction is shown below: 3 NaHCO3(aq) + H3C3H5O7(aq) → Na3C3H5O7(aq) + 3 CO2(g) + 3 H20(l) Devise an experiment to determine the overall order of reaction (be specific in your answer)?
Chapter 7 Solutions
Introduction to General, Organic and Biochemistry
Ch. 7.1 - Problem 7-1 In the reaction we measure the...Ch. 7.4 - Problem 7-2 Calculate the rate for the reaction in...Ch. 7.6 - Prob. 7.3PCh. 7.6 - Prob. 7.4PCh. 7.6 - Prob. 7.5PCh. 7.7 - Prob. 7.6PCh. 7.7 - Problem 7-7 Consider the following equilibrium...Ch. 7.7 - Prob. 7.8PCh. 7.7 - Prob. 7.9PCh. 7 - 7-10 The rate of disappearance of HCI was measured...
Ch. 7 - 7-11 Consider the following reaction: Suppose we...Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 7.14PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 7.27PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 7.30PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 7.42PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 7.44PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - Prob. 7.62PCh. 7 - Prob. 7.63PCh. 7 - 7-64 As we shall see in Chapter 20, there are two...Ch. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 7.70PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Prob. 7.75PCh. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Prob. 7.78PCh. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 7.83PCh. 7 - Prob. 7.84P
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- Problem 7-1 In the reaction we measure the evolution of oxygen gas to determine the rate of reaction. At the beginning of the reaction (at 0 min), 0.020 L of O2 is present. After 15 min, the volume of O2 gas is 0.35 L. What is the rate of reaction?arrow_forwardConsider the following potential-energy curves for two different reactions: a. Which reaction has a higher activation energy for the forward reaction? b. If both reactions were run at the same temperature and have the same orientation requirements to react, which one would have the larger rate constant? c. Are these reactions exothermic or endothermic?arrow_forwardA reaction believed to be either first or second order has a half-life of 20 s at the beginning of the reaction but a half-life of 40 s sometime later. What is the order of the reaction?arrow_forward
- Show the structures of the carbocation intermediates you would expect in the following reactions:arrow_forwardConsider the decomposition of dinitrogen tetroxide, N2O4, to nitrogen dioxide, NO2: N2O4(g)2NO2(g) How would you expect the spontaneity of the reaction to behave with temperature change?arrow_forwardProblem 7-7 Consider the following equilibrium reaction for the decomposition of an aqueous solution of hydrogen peroxide: Oxygen has limited solubility in water (see the table in Chemical Connections 6A). What happens to the equilibrium after the solution becomes saturated with oxygen?arrow_forward
- Experiment Initial [Br–] (M) Initial [BrO3–] (M) Initial [H+] (M) Rate of Disappearance of BrO3– (M s-1) 1 0.00100 0.00500 0.100 2.50x10-4 2 0.00200 0.00500 0.100 5.00x10-4 3 0.00100 0.00750 0.100 3.75x10-4 4 0.00100 0.01500 0.200 3.00x10-3 Determine the order of the reaction for [H+]arrow_forwardThe following Reaction Mechanism is used: A+B+C --> D+E (slow) D+F --> B+X (fast) What is the Catalyst for the mechanism? A, B, C, D, E, F, or there is no catalyst? (answer options)arrow_forwardercise 7.4 Classify each of the following reactions in as many ways as possible. msp;4NH3(g)+5O2(g)4NO(g)+6H2O(g) msp;S8(s)+8O2(g)8SO2(g) msp;2Al(s)+3Cl2(g)2AlCl3(s) msp;2AlN(s)2Al(s)+N2(g) msp;BaCl2(aq)+Na2SO4(aq)BaSO4(s)+2NaCl(aq) msp;2Cs(s)+Br2(l)2CsBr(s) msp;KOH(aq)+HCI(aq)H2O(l)+KCI(aq) msp;2C2H2(g)+5O2(g)4CO2(g)+2H2O(l)arrow_forward
- Exercises20A.1(a) Predict how the total pressure varies during the gas-phase reaction2 ICl(g)+H2(g)→I2(g)+2 HCl(g) in a constant-volume container.20A.1(b) Predict how the total pressure varies during the gas-phase reactionN2(g)+3 H2(g)→2 NH3(g) in a constant-volume container.20A.2(a) The rate of the reaction A+2 B→3 C+D was reported as2.7moldm−3 s−1. State the rates of formation and consumption of theparticipants.20A.2(b) The rate of the reaction A+3 B→C+2 D was reported as2.7moldm−3 s−1. State the rates of formation and consumption of theparticipants.20A.3(a) The rate of formation of C in the reaction 2 A+B→2 C+3 Dis 2.7moldm−3 s−1. State the reaction rate, and the rates of formation orconsumption of A, B, and D.20A.3(b) The rate of consumption of B in the reaction A+3 B→C+2 Dis 2.7moldm−3 s−1. State the reaction rate, and the rates of formation orconsumption of A, C, and D.20A.4(a) The rate law for the reaction in Exercise 20A.2(a) was found to bev=kr[A][B]. What are the units of kr…arrow_forwardDetermine if each of the following statements is true or false (answer T or F). a) A change in temperature will change the value of the equilibrium constant for a 'double-arrow' reaction. b) For an endothermic reaction, the value of Keq (equilibrium constant) will increase if the temperature is increased. c) The value of the rate constant is negative for a 2nd order decomposition reaction. d) A buffer can be prepared by mixing equal amounts of a strong acid and a strong base. e) A catalyst increases the rate of a reaction by lowering the value of the equilibrium constant. please answer allarrow_forwardConsider the dimerization reaction 2A ---> A_2 rate=k[A]^2 When the initial concentration of A is 2.0 M, it requires 30 minutes for 60% of A to react. Calculate the rate constant at these conditions (CORRECT ANSWER is 4.2 x 10^-4 M/s) please help show stepsarrow_forward
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