The compound that has zero dipole moment and higher boiling point. Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified. Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule. Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

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Answer 1

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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1. Using Br2 in C2H4Br2 will result in HBr and ______. a. C2H3Cl3 b. C2H4Cl3 c. C2H2Cl3 d. none of the above 2. How many halogenation are posible in propane? a. 3 b. 8 c. 6 d. 10 3.Sulfonation of pentane will result in ________ and water. a. C5H11SO3H b. C5H12SO3H c. C5H14SO3H d. none of the above 4.Nitration of hexane will result in ________ and water. a. C6H13SO3H b. C6H15NO2 c. C6H13NO2 d. C6H14NO2 5.How many moles of O2 in heating a C12H26 (dodecane) a. 27 b. 37 c. 24 d. none of the above

Rank the following groups in order of decreasing priority. −H, −CH3, −Cl, −CH2Cl

Consider the compounds 1-pentanol,CH3-CH2-CH2-CH2-CH2-OH, melting point -78C boiling point 138C, MW=88.15. 1,6-hexanediol ,HO-CH2-CH2-CH2-CH2-CH2-CH2-OH, mp 42C,bp=250C.MW=118.18. The compound 1,6-hexanediol is more soluble in water than 1-pentanol is. This is because 1,6-hexanediol.... 1) has more carbon atoms 2)has a higher molecular weight 3)has more -OH groups 4)is a solid at room temperature

Answer 2

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 3

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 4

Question

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

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Answer 5

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 6

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 7

Chapter 7.7B, Problem 7.11P

(a)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 8

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 9

(b)

Interpretation Introduction

To determine: The compound that has zero dipole moment and higher boiling point.

Interpretation: The compound that has zero dipole moment and higher boiling point is to be identified.

Concept introduction: The dipole moment gives the polarity of the compound due to polarity difference of the atoms of the compound. It gives the charge separation of the molecule.

Larger the difference in the electronegativies of the atoms, larger is the dipole moment of the molecule. The compound that has high dipole moments has high boiling point due to presence of dipole-dipole attraction.

Answer 10

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 11

(c)

Interpretation Introduction

To determine: The stability of the given compounds and the amount of energy that makes one of them stable.

Interpretation: The stability of the given compound is to be determined and the amount of energy that makes one of them stable is to be calculated.

Concept introduction: The stability of alkenes depends on the structure of alkene. The energy of alkene is measured by their heat of hydrogenation. More the heat of hydrogenation, more stable is the alkene.

Heat of hydrogenation of an alkene is the standard enthalpy for the catalytic hydrogenation of the alkene. The value of heat of hydrogenation is always negative.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.3A - Prob. 7.1P Ch. 7.3A - Prob. 7.2P Ch. 7.3B - Draw five more compounds of formula C4H6NOC1.Ch. 7.3B - For each of the following molecular formulas,...Ch. 7.4 - Give the systematic (IUPAC) names of the following...Ch. 7.5B - The following names are all incorrect. Draw the...Ch. 7.5B - Prob. 7.8P Ch. 7.5B - a. How many stereogcmc double bonds are in...Ch. 7.6 - Teflon-coated frying pans routinely endure...Ch. 7.7B - Prob. 7.11P

Solution Summary: The author analyzes the structure of the compounds with dipole notations.

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