An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water. Concept Introduction : The water mediated solvolysis of halo-compounds follows S N 1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

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Answer 1

Question

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

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(c) Arrange the following compounds in order of increasing acidity, and explain the reasons for your choice of order: phenol, cyclohexanol, 2-fluorocyclohexanol, 2-fluorophenol.

(a) Give the products of the phosphoric acid-catalyzed dehydration of 2-methylcyclohex-3- enol. Label the three products with major, minor, and trace amounts. OH H3PO4, heat (b) Describe the rule that is applied in the acid-catalyzed dehydration of 2-methylcyclohex-3- enol. Explain your answer based on the products formed.

Following is a balanced equation for bromination of toluene.(a) Using the values for bond dissociation enthalpies given in Appendix 3,calculate ∆H0for this reaction.(b) Propose a pair of chain propagation steps and show that they add up to theobserved reaction.(c) Calculate ∆H0for each chain propagation step.(d) Which propagation step is rate-determinin

Answer 2

Question

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

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Answer 3

Question

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

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Answer 4

Question

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

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Answer 5

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

Answer 6

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

Answer 7

Chapter 7.8, Problem 23CC

(a)

Interpretation Introduction

Interpretation:

An explanation regarding which one amongst (2-bromopropan-2-yl) benzene and (2-bromopropan-2-yl) cyclohexane will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follows S_N1 pathway. In this reaction, there are two steps and first step is the carbocation formation step which is the rate determining step.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Explanation regarding which amongst 1-bromo-2-methylpropane and 3-bromo-2-methylprop-1-ene will undergo solvolysis more rapidly in water.

Concept Introduction :

The water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction, there are two steps and the first step is the carbocation formation step which is the rate determining step.

Answer 10

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

Answer 11

(c)

Interpretation Introduction

Interpretation:

It must be clarified whether of the two 1-chloro-2-methylprop-1-ene and 1-bromo-2-methylprop-1-ene will solvolyze more quickly in water.

Concept Introduction :

Water mediated solvolysis of halo-compounds follow S_N1 pathway. In this reaction there are two steps and the first step is the carbocation formation step which is the rate-determining step. Reaction rate increases with a better leaving group.

Answer 12

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Answer 14

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Answer 15

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

Solution Summary: The author explains the water mediated solvolysis of halo-compounds following the S N 1 pathway.

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