ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
4th Edition
ISBN: 9781119760634
Author: Klein
Publisher: WILEY
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Chapter 7, Problem 90ASP
Interpretation Introduction
Interpretation :
It is required to choose which of the provided processes is not a logical retrosynthesis.
Concept Introduction :
A Retrosynthetic analysis helps to disconnect bonds to get suitable starting materials for the synthesis of target molecule.
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In this lab you are performing your first organic synthesis and safety information on all the materials you are using must be obtained.
Companies are required to provide material safety data sheets (MSDS) for chemical compounds they sell.
Please examine the MSDS for acetic anhydride, available here. You will find GHS pictograms within the sheet that summarize the
main hazards of this compound. The pictograms are essentially the same as the symbols on WHMIS labels, available here for
reference.
Based on the pictograms, whatare the main hazards for acetic anhydride? Select as many answers as appropriate
Select one or more:
Carcinogen
Gas under pressure
Acute oral or inhalation toxicity
Corrosive
Flammable material
Oxidizing material
Self-reactive substance
The nature of the primary solvent exclusively influences the miscibility of certain compounds. Toallow the incorporation of lipophilic substances, one must consider using solvents such as propanoland ethyl acetate.
A - If the first statement is TRUE and the second statement is FALSEB - If the first statement is FALSE and the second statement is TRUEC - If both statements are TRUED - If both statements are FALSE
Alcohols are very useful organic compounds because there are many ways to synthesize larger and more
complex molecules starting with simple alcohols. The reactions you will examine form a strong basis for
synthetic tools that an organic chemist would use. You will be expected to predict the major products of
reactions under the conditions given. The key to doing this is to look carefully at the conditions and
remember how those conditions affect the products. It is a good idea to have an index card file of the
reactions as you learn them. Dehydration (loss of water) - There are two forms of dehydration reactions
with alcohols - ether formation and elimination (alkene formation). In both reactions you are looking for
the components of water (OH and H) that will be removed in the reaction. Ether Formation - Two alcohols
will form an ether link by loss of water forming an ether product with an acidic catalyst (typically H2SO4) at
140\deg C. One alcohol loses the hydroxyl group and one…
Chapter 7 Solutions
ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
Ch. 7.2 - Prob. 1CCCh. 7.3 - Prob. 2CCCh. 7.3 - Prob. 1LTSCh. 7.3 - Prob. 3PTSCh. 7.3 - Prob. 4ATSCh. 7.3 - Prob. 2LTSCh. 7.3 - Prob. 5PTSCh. 7.3 - Prob. 6ATSCh. 7.3 - Prob. 7CCCh. 7.4 - Prob. 8CC
Ch. 7.5 - Prob. 9CCCh. 7.6 - Prob. 10CCCh. 7.6 - Prob. 11CCCh. 7.7 - Prob. 12PTSCh. 7.7 - Prob. 13PTSCh. 7.7 - Prob. 14ATSCh. 7.7 - Prob. 4LTSCh. 7.7 - Prob. 16ATSCh. 7.7 - Prob. 17CCCh. 7.7 - Prob. 18CCCh. 7.7 - Prob. 5LTSCh. 7.7 - Prob. 19PTSCh. 7.7 - Prob. 20ATSCh. 7.8 - Prob. 21PTSCh. 7.8 - Prob. 22ATSCh. 7.8 - Prob. 23CCCh. 7.8 - Prob. 24CCCh. 7.8 - Prob. 25CCCh. 7.8 - Prob. 26CCCh. 7.8 - Prob. 27CCCh. 7.9 - Prob. 7LTSCh. 7.9 - Prob. 29ATSCh. 7.9 - Prob. 30ATSCh. 7.9 - Prob. 31ATSCh. 7.10 - Prob. 32CCCh. 7.10 - Prob. 33CCCh. 7.10 - Prob. 34CCCh. 7.11 - Prob. 8LTSCh. 7.11 - Prob. 35PTSCh. 7.11 - Prob. 36PTSCh. 7.11 - Prob. 37ATSCh. 7.11 - Prob. 9LTSCh. 7.11 - Prob. 40PTSCh. 7.11 - Prob. 41ATSCh. 7.12 - Prob. 42CCCh. 7.12 - Prob. 43CCCh. 7.12 - Prob. 44CCCh. 7.12 - Prob. 45CCCh. 7.12 - Prob. 46CCCh. 7 - Prob. 47PPCh. 7 - Prob. 48PPCh. 7 - Prob. 49PPCh. 7 - Prob. 50PPCh. 7 - Prob. 51PPCh. 7 - Prob. 52PPCh. 7 - Prob. 53PPCh. 7 - Prob. 54PPCh. 7 - Prob. 55PPCh. 7 - Prob. 56PPCh. 7 - Prob. 57PPCh. 7 - Prob. 58PPCh. 7 - Prob. 59PPCh. 7 - Prob. 60PPCh. 7 - Prob. 61PPCh. 7 - Prob. 64PPCh. 7 - Indicate whether you would use NaOEt or tBuOK to...Ch. 7 - Prob. 68PPCh. 7 - Draw a plausible mechanism for each of the...Ch. 7 - Prob. 70PPCh. 7 - Prob. 71PPCh. 7 - Prob. 72PPCh. 7 - Prob. 73PPCh. 7 - Prob. 74PPCh. 7 - Prob. 77PPCh. 7 - Prob. 78PPCh. 7 - Prob. 81ASPCh. 7 - Prob. 87ASPCh. 7 - Prob. 90ASPCh. 7 - Prob. 91IPCh. 7 - Prob. 92IPCh. 7 - Prob. 93IPCh. 7 - Prob. 94IPCh. 7 - Prob. 95IPCh. 7 - Prob. 96IPCh. 7 - Prob. 97IPCh. 7 - Prob. 98IPCh. 7 - Prob. 99IPCh. 7 - Prob. 100IPCh. 7 - Prob. 101IPCh. 7 - Prob. 102IPCh. 7 - Prob. 103IPCh. 7 - Prob. 105IPCh. 7 - Prob. 106IPCh. 7 - Prob. 107IPCh. 7 - Prob. 109IPCh. 7 - Prob. 110CPCh. 7 - Prob. 112CPCh. 7 - Prob. 114CP
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