MODERN PHYSICS (LOOSELEAF)
4th Edition
ISBN: 9781119495550
Author: Krane
Publisher: WILEY
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Question
Chapter 8, Problem 27P
(a)
To determine
The effective charge seen by outer electron.
(b)
To determine
The effective charge seen by outer electron in 4f state.
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Students have asked these similar questions
For a K*- CH ion pair, attractive and repulsive energies EA and ER, respectively, depend on
the distance between the ions r, according to
5.8 x 10-6
1.436
EA
and ER
For these expressions, energies are expressed in electron volts per K*- CH pair, and r is the
distance in nanometers.
a) If the net energy EN is just the sum of the two expressions above: EN = E, + ER, Find the
values of ro and E, ?
b) If curves of E, ER, and EN are
plotted in given figure, compare
the calculated values of ro and
E, with that from the graph.
2 am
0.00
010
0.20
0.30
040
0.70
00
1.00
Interatomic Separation, nm
Bonding Energy, eV
a) Calculate the excitation energies for the 1s → 3p electron transition for the H-atom
and for the He+-ion. Calculate the energy values in joules.
b) What is the ionization energy (in eV) of H-atom in the 4d-state?
Note: En
=
2n²
Eh, 1Eh
= 27.2114eV =
2625.500kJ/mol = 4.35974394-10-18 J
For a K*- CF ion pair, attractive and repulsive energies E, and ER, respectively, depend on the distance
between the ions r, according to
1.436
E4 --
5.8 x 10-6
ER =
For these expressions, energies are expressed in electron volts per K*- Cl- pair, and r is the distance in
nanometers.
a) If the net energy EN is just the sum of the two expressions above: EN = E+ ER, Find the values
of r, and E,?
b) If curves of E,, ER and EN are
plotted in given figure, compare
E,
the calculated values of ro and E,
with that from the graph.
-0.28 nm
E,-4.6 eV
0.00
0 10
0.20
0.30
0.40
0.50
060
0.70
0.80
00
1.00
Chapter 8 Solutions
MODERN PHYSICS (LOOSELEAF)
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