Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Textbook Question
Chapter 8, Problem 8.12A
Conceptual APPLY 8.12 Match the following electrostatic potential maps with their corresponding molecule:
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Ammonia reacts with boron trifluoride to form a stablecompound, as we saw in Section 8.7. (a) Draw the Lewisstructure of the ammonia–boron trifluoride reaction product.(b) The B—N bond is obviously more polar than theC—C bond. Draw the charge distribution you expect on theB—N bond within the molecule (using the delta plus anddelta minus symbols mentioned in Section 8.4). (c) Borontrichloride also reacts with ammonia in a similar way tothe trifluoride. Predict whether the B—N bond in the trichloridereaction product would be more or less polar thanthe B—N bond in the trifluoride product, and justify yourreasoning
Ammonia reacts with boron trifluoride to form a stablecompound, as we saw in Section 8.7. (a) Draw the Lewisstructure of the ammonia–boron trifluoride reaction product.(b) The B—N bond is obviously more polar than the C—C bond. Draw the charge distribution you expect on theB—N bond within the molecule (using the delta plus anddelta minus symbols mentioned in Section 8.4). (c) Borontrichloride also reacts with ammonia in a similar way tothe trifluoride. Predict whether the B—N bond in the trichloridereaction product would be more or less polar thanthe B—N bond in the trifluoride product, and justify yourreasoning.
Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfurtetrafluoride monoxide (OSF4) according to the followingunbalanced reaction:
SF4(g) + O2(g)---->OSF4(g)The O atom and the four F atoms in OSF4 are bonded to acentral S atom. (a) Balance the equation. (b) Write a Lewisstructure of OSF4 in which the formal charges of all atomsare zero. (c) Use average bond enthalpies (Table 8.3) to estimatethe enthalpy of the reaction. Is it endothermic or exothermic?(d) Determine the electron-domain geometry ofOSF4, and write two possible molecular geometries for themolecule based on this electron-domain geometry. (e) Foreach of the molecules you drew in part (d), state how manyfluorines are equatorial and how many are axial.
Chapter 8 Solutions
Chemistry - Modified MasteringChemistry
Ch. 8 - Prob. 8.1PCh. 8 - Prob. 8.2ACh. 8 - PRACTICE 8.3 Acetic acid, CH3CO2H , is the main...Ch. 8 - APPLY 8.4 Benzene, C6H6 , is a cyclic molecule in...Ch. 8 - PRACTICE 8.5 Identify the orbitals that overlap to...Ch. 8 - APPLY 8.6 Describe the bonding in propane, C3H8 ,...Ch. 8 - PRACTICE 8.7 Describe the hybridization of the...Ch. 8 - APPLY 8.8 Describe the hybridization of each...Ch. 8 - PRACTICE 8.9 Describe the hybridization of the...Ch. 8 - APPLY 8.10 Describe the hybridization of the...
Ch. 8 - Prob. 8.11PCh. 8 - Conceptual APPLY 8.12 Match the following...Ch. 8 - Prob. 8.13PCh. 8 - Prob. 8.14ACh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16ACh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18ACh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20ACh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22ACh. 8 - PRACTICE 8.23 Draw two resonance structures for...Ch. 8 - APPLY 8.24 Draw two resonance structures for the...Ch. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - PROBLEM 8.27 Identify which of the following...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31CPCh. 8 - Prob. 8.32CPCh. 8 - Prob. 8.33CPCh. 8 - Prob. 8.34CPCh. 8 - Prob. 8.35CPCh. 8 - Prob. 8.36CPCh. 8 - Prob. 8.37CPCh. 8 - Prob. 8.38CPCh. 8 - Prob. 8.39CPCh. 8 - Prob. 8.40CPCh. 8 - Two dichioroethylene molecules with the same...Ch. 8 - Prob. 8.42SPCh. 8 - Prob. 8.43SPCh. 8 - Prob. 8.44SPCh. 8 - How many charge clouds are there around the...Ch. 8 - Prob. 8.46SPCh. 8 - Prob. 8.47SPCh. 8 - What shape do you expect for each of the following...Ch. 8 - Prob. 8.49SPCh. 8 - Prob. 8.50SPCh. 8 - Prob. 8.51SPCh. 8 - Prob. 8.52SPCh. 8 - Prob. 8.53SPCh. 8 - Acrylonitrile is used as the starting material for...Ch. 8 - Predict values for all bond angles in dimethyl...Ch. 8 - Oceanographers study the mixing of water masses by...Ch. 8 - Prob. 8.57SPCh. 8 - Prob. 8.58SPCh. 8 - Prob. 8.59SPCh. 8 - Prob. 8.60SPCh. 8 - Prob. 8.61SPCh. 8 - Prob. 8.62SPCh. 8 - Prob. 8.63SPCh. 8 - Prob. 8.64SPCh. 8 - Prob. 8.65SPCh. 8 - Oxaloacetic acid is an intermediate involved in...Ch. 8 - The atoms in the amino acid glycine are connected...Ch. 8 - Prob. 8.68SPCh. 8 - Prob. 8.69SPCh. 8 - Prob. 8.70SPCh. 8 - 8.71 What is the difference between London...Ch. 8 - 8.72 What are the most important kinds of...Ch. 8 - Of the substances Xe,CH3Cl,HF, which has: (a) The...Ch. 8 - 8.74 Methanol boils nearlyhigher than methane, but...Ch. 8 - Prob. 8.75SPCh. 8 - Prob. 8.76SPCh. 8 - Prob. 8.77SPCh. 8 - Prob. 8.78SPCh. 8 - Prob. 8.79SPCh. 8 - Prob. 8.80SPCh. 8 - 8.81 Draw three-dimensional structures of PCl3 and...Ch. 8 - Prob. 8.82SPCh. 8 - Prob. 8.83SPCh. 8 - Prob. 8.84SPCh. 8 - Prob. 8.85SPCh. 8 - 8.86 A liquid sample contains methylamine (CH3NH2)...Ch. 8 - Prob. 8.87SPCh. 8 - Prob. 8.88SPCh. 8 - Prob. 8.89SPCh. 8 - Prob. 8.90SPCh. 8 - Prob. 8.91SPCh. 8 - Prob. 8.92SPCh. 8 - Prob. 8.93SPCh. 8 - Prob. 8.94SPCh. 8 - Prob. 8.95SPCh. 8 - Prob. 8.96SPCh. 8 - Prob. 8.98CPCh. 8 - Prob. 8.99CPCh. 8 - Prob. 8.100CPCh. 8 - Prob. 8.101CPCh. 8 - Prob. 8.102CPCh. 8 - Prob. 8.103CPCh. 8 - Prob. 8.104CPCh. 8 - Prob. 8.105CPCh. 8 - Prob. 8.106CPCh. 8 - Prob. 8.107CPCh. 8 - Prob. 8.108CPCh. 8 - Prob. 8.109CPCh. 8 - The odor of cinnamon oil is due to cinnamaldehyde,...Ch. 8 - Prob. 8.111CPCh. 8 - Prob. 8.112CPCh. 8 - Prob. 8.113CPCh. 8 - Prob. 8.114CPCh. 8 - Prob. 8.115CPCh. 8 - Prob. 8.116CPCh. 8 - Prob. 8.117CPCh. 8 - Prob. 8.118CPCh. 8 - Prob. 8.119MPCh. 8 - Prob. 8.120MPCh. 8 - Prob. 8.121MP
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