Interpretation:
Balanced equation for the reaction of methane and iodine to give methyl iodide and hydrogen iodide has to be given and
Concept introduction:
Halogenation of
It is a change in enthalpy of a homolytic reaction at absolute zero where a molecule is broken down into two free radicals.
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Chapter 8 Solutions
OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
- Write a balanced equation and calculate ▲H° for reaction of CH4 and I2 to give CH3I and HI. Explain why this reaction cannot be used as a method of preparation of iodomethane.arrow_forward2,2,3,3-Tetrabromopentane can be prepared by an addition reaction of excess Br2 with an alkyne. Draw the structure of the alkyne and name it.arrow_forwardHydrocarbon S, C8H8 reacts with hydrogen in the presence of platinum catalyst to yield T, C8H10. Compound U is formed when T is heated with alkaline potassium permanganate solution, followed by hydrolysis. The reaction of S with hydrogen bromide V, whereas ozonolysis of S produces W and methanal. Draw the structures of S to W. Give the name of the reaction for the conversion of S to T. Write all chemical equations involved.arrow_forward
- Reaction of (CH3)3CH with Cl2 forms two products: (CH3)2CHCH2Cl (63%) and (CH3)3CCl (37%). Why is the major product formed by cleavage of the stronger 1° C–H bond?arrow_forwardWrite an equation for the reaction of chloroacetic acid (Ka=1.5103) with trimethylamine (Kb=5.9105) . Calculate the equilibrium constant for the reaction. If 0.10 M solutions of these two species are mixed, what will be their concentrations at equilibrium?arrow_forwardComplete and balance the following combustion reactions. Assume that each hydrocarbon is converted completely to carbon dioxide and water. (a) Propane + O2 (b) Octane + O2 (c) Cyclohexane + O2 (d) 2-Methylpentane + O2arrow_forward
- When aniline, C6H5NH2(Kb=7.41010) , reacts with a strong acid, its conjugate acid, C6H5NH3+, is formed. Calculate the pH of a 0.100 M solution of C6H5NH3+ and compare it with the pH of acetic acid (Ka=1.86105) .arrow_forwardAccount for the following:(i) The C – Cl bond length in chlorobenzene is shorter than that in CH3 – Cl.(ii) Chloroform is stored in closed dark brown bottles.arrow_forward5 Isopropylbenzene (C9H12) is commercially produced by Friedel–Crafts alkylation of compound H with 1-chloropropane in the presence of anhydrous aluminium chloride as a catalyst. CyH12 can be oxidized with strong oxidizing agent to form compound J. a) Draw the structure of H. b) Write the chemical reaction of isopropylbenzene to form compound J. c) Show the mechanism for the formation of isopropylbenzene (C,H12) from compound H. C,H¬B1+ OH¯→ C,H¬OH + NaBr The rate equation for the hydrolysis of C3H,Br with sodium hydroxide is: rate = k [C3H»Br] [OH ¯] a) Draw the structural formula of C3H¬Br. Explain your answer. b) State and show the mechanism of the reaction above. An alkyl halide E, C5H11B undergoes hydrolysis to form an alcohol F, CSH120. Alcohol F becomes cloudy immediately when reacted with a Lucas reagent. c) (i) (ii) Deduce the structures of E and F. State the type of reaction and propose the mechanism for the conversion of E to F. d) Draw the structure of the product formed…arrow_forward
- Compound E is a branched molecule with the molecular formula of CH140. Compound E reacted with hot concentrated phosphoric acid to form Compound F (major product). Compound G was produced when Compound F reacted with hydrogen gas in the presence of platinum while Compound H was produced when Compound F reacted with Br2 in H20. Compound F reacted with hydrogen bromide in the presences of hydrogen peroxide to form Compound I. Compound J formed when Compound F reacted with cold dilute manganate (VII) ions while Compound K formed when Compound F reacted with hot acidified concentrated potassium permanganate. Compound I was heated with aqueous sodium hydroxide to produce Compound L. Compound M was produced when Compound I reacted with aqueous ammonia in ethanol while Compound N was produced when Compound I reacted with sodium cyanide. Identify the possible structural formulae for compound E to N. State ONE test to differentiate between Compound F and Compound G. Give TWO differences between…arrow_forwardWhat is the structure of C8H10O2? ( If the following information is given, please show the steps. )arrow_forwardWhy is benzene less reactive than hexane in terms of stability of free radicals?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
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