Chemistry: An Atoms-Focused Approach
1st Edition
ISBN: 9780393124200
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Calcium oxalate, CaCO4, is very insoluble in water. What mass of sodium oxalate,Na2C2O4, is required to precipitate the calcium ion from 37.5 mL of 0.104 M CaCl2solution?
Given the equation
Ag(aq)+ + 2NH3(aq) ----> [Ag(NH3)2]+(aq), determine the concentration of NH3(aq) that is required to dissolved 261mg of AgCl in 100 ml of solution. The Ksp of AgCl is 1.77 x 10-10 Kf = 2 x 107.
Consider an analyte solution of 50.0 mL of 0.050 M hydrochloric acid, HCl, titrated against 0.10 M sodium hydroxide, NaOH
(d) After adding 12.50 mL of the NaOH, halfway to the equivalence point, what ions or molecules are present in the solution?
(e) At the equivalence point, after adding 25.00 mL of NaOH, what ions or molecules are present in the solution?
(f) Which of the species you identified in part (e) will determine the pH of the solution?
Chapter 8 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 8 - Prob. 8.1VPCh. 8 - Prob. 8.2VPCh. 8 - Prob. 8.3VPCh. 8 - Prob. 8.4VPCh. 8 - Prob. 8.5VPCh. 8 - Prob. 8.6VPCh. 8 - Prob. 8.7VPCh. 8 - Prob. 8.8VPCh. 8 - Prob. 8.9VPCh. 8 - Prob. 8.10VP
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- A student is given 0.930 g of an unknown acid, which can be either oxalic acid, H2C2O4, or citric acid, H3C6H5O7. To determine which acid she has, she titrates the unknown acid with 0.615 M NaOH. The equivalence point is reached when 33.6 mL are added. What is the unknown acid?arrow_forwardBecause barium sulfate is opaque to X-rays, it is suspended in water and taken internally to make the gastrointestinal tract visible in an X-ray photograph. Although barium ion is quite toxic, barium sulfate’s Ksp of 1.1 x 10–10 gives it such low solubility that it can be safely consumed. (a) What is the molar solubility of BaSO4? (b) What is its solubility in grams per 100 g of water?arrow_forwardWhat is the normality of 50.0 ml Ba(OH)2 solution when titrated with 23.50 mL of 0.250 N HCl? MM BaOH2 = 171.3 g/molMM HCl = 36.46 g/molarrow_forward
- 3. how would the following errors affect the concentration of Cl- obtained in question 2b? give your reasoning in each case. a. the student read the molarity of AgNo3 as 0.02104M instead of 0.02014M b. the student was past the endpoint of titration when he took the final buret reading.arrow_forward4 A sample of solid Ca(OH)2 was stirred in water at a certain temperature until the solution contained as much dissolved Ca(OH)2 as it could hold. A 84.3-mL sample of this solution was withdrawn and titrated with 0.0771 M HBr. It required 86.7 mL of the acid solution for neutralization. (a) What was the molarity of the Ca(OH)2 solution? M (b) What is the solubility of Ca(OH)2 in water, at the experimental temperature, in grams of Ca(OH)2 per 100 mL of solution? g/100mLarrow_forwardWhat volume (in ml) of 0.12 M HBr solution is be required to titrate 125 mL of a 0.1 M Ca(OH)2 solution? Ca(OH)2(aq) + 2HBr(aq) ⟶ CaBr2(aq) + 2H2O(l)arrow_forward
- a) Copper(I) ions in aqueous solution react with NH3(aq)NH3(aq) according to Cu+(aq)+2NH3(aq)⟶Cu(NH3)+2(aq)?f=6.3×10^10 Calculate the solubility (in g·L−1) of CuBr(s)CuBr(s) (?sp=6.3×10−9Ksp=6.3×10−9) in 0.19 M0.19 M NH3(aq)NH3(aq). solubility of CuBr(s)CuBr(s): g/L b) Given the equation Ag+(aq)+2NH3(aq)⟶[Ag(NH3)2]+(aq)?f=2.00×107Ag+(aq)+2NH3(aq)⟶[Ag(NH3)2]+(aq)Kf=2.00×107 determine the concentration of NH3(aq) that is required to dissolve 589589 mg of AgCl(s) in 100.0 mL of solution. The ?spKsp of AgCl is 1.77×10−101.77×10−10. [NH3]= c) The formation constant* of [M(CN)44]2− is 7.70×10167.70×1016, where M is a generic metal. A 0.1400.140 mole quantity of M(NO3)2 is added to a liter of 0.9700.970 M NaCN solution. What is the concentration of M2+ ions at equilibrium? [M2+]=arrow_forwardThe active ingredient in a certain toilet cleaner that claims to ‘remove lime scale and rust’ is hydrochloric acid of approximate concentration 1.12 mol/L. To analyze this toilet cleaner, a quality control chemist first delivered a 16.2 mL aliquot of the toilet cleaner into a 250-mL volumetric flask, then made up the diluted solution. She then titrated a 24.8 mL aliquot of this diluted solution against standard sodium hydroxide solution of concentration 0.2178 mol/L. The expected titre (or volume of the titrant) would be approximately:arrow_forwardA student analyzed an antacid tablet from a bottle of 50 tables purchased at a discount store for $1.00. The mass of the tablet was 1.470 g.After adding 25.00 mL of 0.7989 M HCl solution to the tablet, the student back-titrated the excess HCl with 3.55 mL of 1.017 M NaOHsolution. Calculate the number of moles of stomach acid neutralized by one Calculate the mass effectiveness of the tablet (mol H+/g). Calculate the cost effectiveness of one tablet ($/mol H+).arrow_forward
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