Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 8, Problem 8.20P
To determine
The upper bound on the energy of the first excited state of the hydrogen atom.
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Introduction To Quantum Mechanics
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- A simple illustration of the variation method is provided by the hydrogen atom in the 1s state. Let us assume a form of the trial wave function ψ=e–br where b is a constant. For hydrogen atom, V=-e2/r, so the Hamiltonian operator is Ĥ=-h2/8π2m V2- e2/r.The energy depends on r for the 1s state of the hydrogen atom so the angular portion of the Laplacian can be omitted and replaced by the factor 4π after integration. Therefore, the radial portion of V2=1/r2 (∂/∂r) r2 ∂/∂r. Solve the energy minimum of the hydrogen atom, E = -2π2 me4/h2.arrow_forwardDerive the Nernst Equation from the definition of the free energy, G.arrow_forwardA point particle moves in space under the influence of a force derivablefrom a generalized potential of the formU(r, v) = V (r) + σ · L,where r is the radius vector from a fixed point, L is the angular momentumabout that point, and σ is the fixed vector in space. Find the components of the force on the particle in spherical polar coordinates, on the basis of the equation for the components of the generalized force Qj: Qj = −∂U/∂qj + d/dt (∂U/∂q˙j)arrow_forward
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