Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested. Concept introduction: Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step. The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

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Answer 1

Question

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

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Answer 2

Question

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

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Answer 3

Question

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

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Answer 4

Question

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

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Answer 5

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

Answer 6

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

Answer 7

Chapter 8, Problem 8.26P

Interpretation Introduction

Interpretation:

Why the mechanism for the overall reaction is unreasonable is to be explained. An alternate, more reasonable mechanism is to be suggested.

Concept introduction:

Mechanism of a reaction may be made up of a number of elementary steps. An elementary step generally involves only one or two reactant molecules. An elementary step involving three or more molecules is extremely rare because it would involve a collision of three (or more) molecules at exactly the same moment and also in a particular orientation. This is extremely rare, and therefore, an unreasonable step.

The species involved in a proposed elementary step should be compatible with the reaction conditions, particularly pH.

Answer 8

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Answer 10

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Answer 11

Ch. 8 - Prob. 8.1P Ch. 8 - Prob. 8.2P Ch. 8 - Prob. 8.3P Ch. 8 - Prob. 8.4P Ch. 8 - Prob. 8.5P Ch. 8 - Prob. 8.6P Ch. 8 - Prob. 8.7P Ch. 8 - Prob. 8.8P Ch. 8 - Prob. 8.9P Ch. 8 - Prob. 8.10P

Solution Summary: The author explains why the mechanism for the overall reaction is unreasonable, and suggests an alternate, more reasonable mechanism.

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