Chemistry: The Molecular Nature of Matter and Change
Chemistry: The Molecular Nature of Matter and Change
8th Edition
ISBN: 9781259631757
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Chapter 8, Problem 8.52P
Interpretation Introduction

Interpretation:

The influence of d-electron shielding on the atomic size among the period 4 transition elements is to be determined.

Concept introduction:

The shielding effect is the reduction in the effective nuclear charge on the electron cloud due to the difference in the attractive forces with the nucleus Greater the screening effect, easier will be the removal of electrons. It occurs when the inner electrons shield the outer electrons from the full nuclear attractive force. This is also known as atomic or electron shielding.

The order of the shielding effect of the various orbitals is as follows:

s>p>d>f

Atomic size is defined as the distance between the nucleus and the outermost shell of the atom where the valence electrons are located. It increases when we move from top to bottom in a group due to increase in the number of shells of the successive members and it decreases when we move from left to right along a period due to increase in the effective nuclear charge in the successive members.

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Chapter 8 Solutions

Chemistry: The Molecular Nature of Matter and Change

Ch. 8.4 - Prob. 8.6AFPCh. 8.4 - Prob. 8.6BFPCh. 8.4 - Prob. 8.7AFPCh. 8.4 - Prob. 8.7BFPCh. 8.4 - Prob. 8.8AFPCh. 8.4 - Prob. 8.8BFPCh. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - To test Döbereiner’s idea (Problem 8.3),...Ch. 8 - Summarize the rules for the allowable values of...Ch. 8 - Prob. 8.6PCh. 8 - State the exclusion principle. What does it imply...Ch. 8 - What is the key distinction between sublevel...Ch. 8 - Prob. 8.9PCh. 8 - Prob. 8.10PCh. 8 - Prob. 8.11PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.13PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.15PCh. 8 - State Hund’s rule in your own words, and show its...Ch. 8 - Prob. 8.17PCh. 8 - For main-group elements, are outer electron...Ch. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Write the full ground-state electron configuration...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.29PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Draw the partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - How many inner, outer, and valence electrons are...Ch. 8 - How many inner, outer, and valence electrons are...Ch. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - If the exact outer limit of an isolated atom...Ch. 8 - Given the following partial (valence-level)...Ch. 8 - In what region of the periodic table will you find...Ch. 8 - Why do successive IEs of a given element always...Ch. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - What is a pseudo-noble gas configuration? Give an...Ch. 8 - How are measurements of paramagnetism used to...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - Prob. 8.79PCh. 8 - Prob. 8.80PCh. 8 - Which of these atoms are paramagnetic in their...Ch. 8 - Prob. 8.82PCh. 8 - Prob. 8.83PCh. 8 - Write the condensed ground-state electron...Ch. 8 - Prob. 8.85PCh. 8 - Prob. 8.86PCh. 8 - Rank the ions in each set in order of increasing...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - A fundamental relationship of electrostatics...Ch. 8 - Prob. 8.93PCh. 8 - Prob. 8.94PCh. 8 - Prob. 8.95PCh. 8 - Prob. 8.96PCh. 8 - Prob. 8.97PCh. 8 - Prob. 8.98PCh. 8 - Use Figure 8.16, to find: (a) the longest...Ch. 8 - Prob. 8.100PCh. 8 - Prob. 8.101PCh. 8 - Prob. 8.102P
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