From the given reactions, an efficient method to synthesis given alcohol has to be predicted. Concept Introduction: Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition. An acid-catalysed hydration is shown below. Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides. Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition. Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 1

Question

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 2

Question

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 3

Question

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 4

Question

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 5

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 6

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 7

Chapter 8, Problem 91IP

Interpretation Introduction

Interpretation:

From the given reactions, an efficient method to synthesis given alcohol has to be predicted.

Concept Introduction:

Simple hydration in acidic media gives the addition product through carbocation intermediate and follows Markovnikov addition.

An acid-catalysed hydration is shown below.

Markovnikov’s rule: An unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Hydroboration-oxidation reaction: Addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. It follows Anti-Markovnikov addition.

Anti-Markovnikov’s rule: In the presence of per acid, an unsymmetrical alkene reacts with hydrogen halide in which halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 8

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Answer 11

Ch. 8.4 - Prob. 1CC Ch. 8.4 - Prob. 2CC Ch. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTS Ch. 8.4 - Prob. 4ATS Ch. 8.4 - Prob. 5CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 6PTS Ch. 8.5 - Prob. 8CC Ch. 8.5 - Prob. 9CC

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