The reagents that perform given transformation has to be identified. Concept introduction: Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene. Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound. Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

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Answer 1

Question

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

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Answer 2

Question

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

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Answer 3

Question

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

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Answer 4

Question

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

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Answer 5

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 6

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 7

Chapter 8.14, Problem 39PTS

(a)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The reagents that perform given transformation has to be identified.

Concept introduction:

Elimination reaction: In elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: In addition reaction, two substituents are added to the reactant without losing any compound.

Hydro-halogenation: Hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 8.4 - Prob. 1CC Ch. 8.4 - Prob. 2CC Ch. 8.4 - Draw a mechanism for the following...Ch. 8.4 - Prob. 3PTS Ch. 8.4 - Prob. 4ATS Ch. 8.4 - Prob. 5CC Ch. 8.4 - Prob. 2LTS Ch. 8.4 - Prob. 6PTS Ch. 8.5 - Prob. 8CC Ch. 8.5 - Prob. 9CC

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