ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
ORGANIC CHEMISTRY WILEYPLUS ACCESS>I<
4th Edition
ISBN: 9781119850151
Author: Klein
Publisher: WILEY
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Chapter 8.3, Problem 2CC

(a)

Interpretation Introduction

Interpretation: The bond-line structure of 3-isopropyl-2,4-dimethyl-2-pentene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

(b)

Interpretation Introduction

Interpretation: The bond-line structure of 4-ethyl-2-methyl-2-hexene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

(c)

Interpretation Introduction

Interpretation: The bond-line structure of 1,2-dimethylcyclobutene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

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C. Butane Measurements: Strain energy—anti conformation 10. C1–C2–C3 bond angle—anti 11. H–C1–C2 bond angle—anti 12. C1–C2–C3–H dihedral angle—anti 13. Strain energy—gauche conformation 14. C1–C2–C3 bond angle—gauche 15. C1–C2–C3–C4 dihedral angle—gauche 16. C1–C4 H–H distance—gauche 17. H–C1–C2–C3 dihedral angle—gauche 18.
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