CHEMISTRY: MOLECULAR...V2SSM <CUSTOM>
CHEMISTRY: MOLECULAR...V2SSM <CUSTOM>
9th Edition
ISBN: 9781265922610
Author: SILBERBERG
Publisher: MCG CUSTOM
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Chapter 8.4, Problem 8.6AFP

(a)

Interpretation Introduction

Interpretation:

The condensed electronic configuration of V3+(Z=23) is to be determined. Also whether V3+ is paramagnetic or not is to be determined.

Concept introduction:

The electronic configuration of an element tells about the distribution of electrons in the atomic orbitals. It is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The condensed electronic configuration is a short way to write the configuration of elements in terms of the nearest noble gas configuration.

The electrons are filled up in accordance with three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

A species containing an unpaired number of electrons is said to be paramagnetic species and the species containing only paired electrons is said to be diamagnetic species.

(b)

Interpretation Introduction

Interpretation:

The condensed electronic configuration of Ni2+(Z=28) is to be determined. Also whether Ni2+ is paramagnetic or not is to be determined.

Concept introduction:

The electronic configuration of an element tells about the distribution of electrons in the atomic orbitals. It is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The condensed electronic configuration is a short way to write the configuration of elements in terms of the nearest noble gas configuration.

The electrons are filled up in accordance with three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

A species containing an unpaired number of electrons is said to be paramagnetic species and the species containing only paired electrons is said to be diamagnetic species.

(c)

Interpretation Introduction

Interpretation:

The condensed electronic configuration of La3+(Z=57) is to be determined. Also whether La3+  is paramagnetic or not is to be determined.

Concept introduction:

The electronic configuration of an element tells about the distribution of electrons in the atomic orbitals. It is used to predict the physical, chemical, electrical and magnetic properties of the substance.

The condensed electronic configuration is a short way to write the configuration of elements in terms of the nearest noble gas configuration.

The electrons are filled up in accordance with three rules:

1. Aufbau principle which states that the electrons are filled up in the increasing order of their orbitals which follows as: 1s2s2p3s3p4s3d.

2. Hund’s rule which states that the pairing of electrons will not start until each of the orbitals is singly occupied.

3. Pauli’s exclusion principle states that no two electrons can have the same value of all the four quantum numbers.

A species containing an unpaired number of electrons is said to be paramagnetic species and the species containing only paired electrons is said to be diamagnetic species.

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Chapter 8 Solutions

CHEMISTRY: MOLECULAR...V2SSM <CUSTOM>

Ch. 8.4 - Prob. 8.6AFPCh. 8.4 - Prob. 8.6BFPCh. 8.4 - Prob. 8.7AFPCh. 8.4 - Prob. 8.7BFPCh. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - To test Döbereiner’s idea (Problem 8.3),...Ch. 8 - Summarize the rules for the allowable values of...Ch. 8 - Prob. 8.6PCh. 8 - State the exclusion principle. What does it imply...Ch. 8 - What is the key distinction between sublevel...Ch. 8 - Prob. 8.9PCh. 8 - Prob. 8.10PCh. 8 - Prob. 8.11PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.13PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.15PCh. 8 - State Hund’s rule in your own words, and show its...Ch. 8 - Prob. 8.17PCh. 8 - For main-group elements, are outer electron...Ch. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Write the full ground-state electron configuration...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.29PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Draw the partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - How many inner, outer, and valence electrons are...Ch. 8 - How many inner, outer, and valence electrons are...Ch. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - If the exact outer limit of an isolated atom...Ch. 8 - Given the following partial (valence-level)...Ch. 8 - In what region of the periodic table will you find...Ch. 8 - Why do successive IEs of a given element always...Ch. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - What is a pseudo-noble gas configuration? Give an...Ch. 8 - How are measurements of paramagnetism used to...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - Prob. 8.79PCh. 8 - Prob. 8.80PCh. 8 - Which of these atoms are paramagnetic in their...Ch. 8 - Prob. 8.82PCh. 8 - Prob. 8.83PCh. 8 - Write the condensed ground-state electron...Ch. 8 - Prob. 8.85PCh. 8 - Prob. 8.86PCh. 8 - Rank the ions in each set in order of increasing...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - A fundamental relationship of electrostatics...Ch. 8 - Prob. 8.93PCh. 8 - Prob. 8.94PCh. 8 - Prob. 8.95PCh. 8 - Prob. 8.96PCh. 8 - Prob. 8.97PCh. 8 - Prob. 8.98PCh. 8 - Use Figure 8.16, to find: (a) the longest...Ch. 8 - Prob. 8.100PCh. 8 - Prob. 8.101PCh. 8 - Prob. 8.102P
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