Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 9, Problem 32QAP
When yeast is added to a solution of glucose or fructose, the sugars are said to undergo fermentation, and ethyl alcohol is produced.
:math>
is is the reaction by which wines arc produced from grape juice. Calculate the mass of ethyl alcohol,
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Industrial production of nitric acid, which is used in many products including fertilizers and explosives, approaches 10 billion kg per year worldwide. The first step in its production is the exothermic oxidation of ammonia, represented by the following equation.
4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g)
ΔH⁰rxn
= −902.0 kJ
If this reaction is carried out using 7.007 ✕ 103 g NH3 as the limiting reactant, what is the change in enthalpy?
When in danger, bombardier beetles can fire a hot, toxic mixture of chemicals at their attacker. This
mixture contains quinone, C6H4O2, a compound that is formed by the reaction of hydroquinone, CH4(OH)2,
with hydrogen peroxide, H2O2. The equation for the overall reaction is:
CH4(OH)2(aq) + H2O2(aq) → C6H4O2(aq) + 2H2O(ℓ)
Use the following data to calculate the enthalpy change, in kJ mol-1
, for the above reaction.
CH4(OH)2(aq) → C6H4O2 (aq) + H2(g) ΔH = +177.4 kJ mol−1
H2(g) + O2(g) → H2O2(aq) ΔH = −191.2 kJ mol−1
H2(g) + ½O2(g) → H2O(g) ΔH = −241.8 kJ mol−1
H2O(g) → H2O(ℓ) ΔH = −43.8 kJ mol−1
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- The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forwardWhen one mole of ethylene gas, C2H4, reacts with fluorine gas, hydrogen fluoride and carbon tetrafluoride gases are formed and 2496.7 kJ of heat are given off. What is Hf for CF4(g)?arrow_forwardCarbon dioxide from the atmosphere weathers, or dissolves, limestone (CaCO3) by the reaction CaCO3(s)+CO2(g)+H2O(l)Ca2(aq)+2HCO3(aq) Obtain H for this reaction. See Table 6.2 for the data.arrow_forward
- Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)arrow_forwardA rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.arrow_forward4.72 The picture shown depicts the species present at the start of a combustion reaction between methane, CH4 and oxygen, O2 (a) What is the limiting reactant? (b) Draw the resulting state after this set of reactants has reacted as far as possible.arrow_forward
- 4-77 To convert 1 mol of iron(III) oxide to its elements requires 196.5 kcal: How many grams of iron can be produced if 156.0 kcal of heat is absorbed by a large-enough sample of iron(III) oxide?arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forwardWhen potassium chlorate is subjected to high temperatures, it decomposes into potassium chloride and oxygen. (a) Write a balanced equation for the decomposition. (b) In this decomposition, the actual yield is 83.2%. If 198.5 g of oxygen are produced, how much potassium chlorate decomposed?arrow_forward
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